镁合金腐蚀测试与分析研究进展
黄居峰, 宋光铃

Research Progress on Corrosion Testing and Analysis of Mg-alloys
HUANG Jufeng, SONG Guangling
表2 微区电化学技术的特性和优缺点[4]
Table 2 Characteristics, advantages and disadvantages of micro-electrochemical technology[4]
TechniqueMeasurementAdvantageDisadvantage
Scanning Vibration Electrode Technique (SVET)

Potential Difference/Current

Density

Real time mechanistic information, 2D-3D data presentation, easy to set up, easily used with other techniques such as SIET

Time and sample size tradeoff, could be slow, cannot use high conductivity electrolyte

of electrolyte is a concern

Scanning Electrochemical Microscopy (SECM)

Current/

Potential

Several modes of operation, can be combined with other techniquesSometimes needs a redox active mediator, needs a bipotentiostat

Localized EIS (LEIS)

Local Capacitance

and Resistance

High sensitivity (1 nV), provides local impedance which cannot be obtained by any other method, good for insulated substrates

Stray inductance, could be slow

Scanning Kelvin Probe (SKP)Work FunctionNo need of an electrolyte, short experimentsLow resolution of SKP
Scanning Ion-Selective Electrode TechniqueLocal pH, ion concentrationCan be combined with SVET, easy way to measure ion concentrationFouling and damage to the ion selective electrode, resolution