非晶合金耐蚀性研究进展

王东亮, 丁华平, 马云飞, 龚攀, 王新云

Research Progress on Corrosion Resistance of Metallic Glasses

WANG Dongliang, DING Huaping, MA Yunfei, GONG Pan, WANG Xinyun

表1 添加合金元素对非晶合金耐蚀性的影响总结

Table 1 Summary of the effect of adding alloying elements on corrosion resistance

Element Content x(Atomic fraction / %) Base alloy (Atomic fraction / %) Corroding solution Effect on corrosion resistance References Sr 0~1% Mg66Zn30Ca4-xSrx Phosphate-buffered saline Enhanced [33] 1%~1.5% Deteriorated Y 0~2.5% (Zr58Nb3Cu16Ni13Al10)100-xYx 0.5 mol/L H2SO4 Deteriorated [30] 1% (Zr55Al10Cu30Ni5)99Yx Phosphate-buffered saline Enhanced [20] Nb 0~20% Zr46Cu(30.14-x)NbxAg8.36Al8Be7.5 0.1 mol/L HCl Enhanced [34] 0.5 mol/L NaCl Enhanced 0.5 mol/L H2SO4 Enhanced Nd 0~0.5% Mg68-xZn28Ca4Ndx Simulated body fluid Enhanced [25] 0.5%~1.5% Deteriorated Cr 0~30% CrxFe56-xCo7Mo14C15B6Y2 1 mol/L HCl Enhanced [32] 30%~45% No difference 0~29.4% CrxFe58.8-xMo14.7C14.7B9.8Y2 1 mol/L HCl Enhanced [35] 29.4%~44.1% No difference 0~8.3% Fe71.4-xC7.1Si4.4B6.5P8.6CrxAl2.0 9.7 mol/L H2SO4 Enhanced [22] 8.3%~12.3% Deteriorated 0~5% Fe79.5-xSi9.5B11Crx 0.1 mol/L NaCl Enhanced [36] B 0~5% Zr66.7-xNi33.3Bx 0.5 mol/L NaCl B0.3＞B0.1, B0.5＞B0 [19] 1 mol/L HCl B0.5＞B0.1, B0.3＞B0 2 mol/L NaOH B0.1＞B0.5＞B0.3, B0 Co 0~4% (Zr46Cu46Al8)100-xCox 3.5%NaCl Enhanced [28] Ti 0~4% (Cu37.6Zr46Ag8.4Al8)100-xTix 1 mol/L NaOH Enhanced [26] 1 mol/L H2SO4 Enhanced 1 mol/L H2SO4+0.01 mol/L NaCl Enhanced 1 mol/L H2SO4+0.1 mol/L NaCl Enhanced Ag 0~9% Zr53Co23.5-xAl23.5Agx Phosphate-buffered saline Enhanced [29] Si 0~2% Fe85.2SixB9P5-xCu0.8 Boric-borate buffer solution Enhanced [37] C 0~3% Fe73.5Cu1Nb3Si13.5CxB99-x 0.1 mol/L H2SO4 Enhanced [38] Mn 0~1.5% (Mg65Zn30Ca5)100-xMnx Simulated body fluid Deteriorated [24] Ce 3%~7% Al93-xCo7Cex 0.6 mol/L HCl Ce4 is the best [39] Au 0~3% Ca47Mg18Zn35-xAux Ringer's solution Enhanced [40] P 0~15% Fe43Cr16Mo16(C, B, P)25 1, 6, 12 mol/L HCl P＞B, C [21] Ni 0~0.4% [(Fe1-xNix)0.75B0.2Si0.05]96Nb4 0.5 mol/L HCl Enhanced [27] 0.5 mol/L H2SO4 Enhanced 0.5 mol/L NaOH Enhanced Hf 0~5% Zr55Ti3HfxCu32-xAl10 0.6 mol/L NaCl Enhanced [31] 1 mol/L HCl Enhanced 1 mol/L H2SO4 Enhanced