机械摩擦磨损与电化学腐蚀在特殊环境中的作用机制
陈嘉晨,王忠维,乔利杰,岩雨

Interaction between Friction-wear and Corrosion in Special Environment
Jiachen CHEN,Zhongwei WANG,Lijie QIAO,Yu YAN
表1 腐蚀/表面上的影响因素
Table 1 Influencing factors of corrosion/surface
Contact stateRelated reaction
Contact load and form

1. Contact pressure (surface and subsurface) and contact area

2. Elastic or elastic-plastic or complete plastic reactions on surfaces and subsurfaces

3. Surface deformation (elastic or permanent deformation)

Relative motion under loading conditions (causing wear in corrosive environments)

1. Depassivation of passivated surfaces

2. Corrosion potential (mixed potential of wear and non-wear area)

3. Causing phase transition on the surface or near the surface

4. Repassivation kinetics

5. Local mass transfer acceleration

6. Increase in contact temperature

7. Increase in roughness and corresponding area

8. Change of surface composition

9. Formation of a mechanical mixing layer, which may contain debris

10. Wear area and the non-wear area constitute a couple pair

11. Cause surface hardening

12. Affects the shear strength of rough/rough surface joints and causes adhesion

Changing load in dynamic contact

1. Self-corrosion potential

2. Local current density

3. Area of active anode and anode site position[4]

4. Surface recovery time

5. Change the wear mechanism or wear rate

Frictionr- corrosion

1. Effect of friction

2. Local environmental pH

3. Total surface loss (mechanical and electrochemical)

Wear debrisResulting metal abrasives corrode in the environment causing secondary release of ions