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J Chin Soc Corr Pro  2009, Vol. 29 Issue (1): 15-18    DOI:
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EFFECT OF THE SAMPLE STATE ON DECHROMIZATION OF Cu-Cr ALLOY
FAN Liru1;LIU Yuwen2;WANG Kuan3;LI Yuan2;SUN Qina4
1.College of Science; Yanshan University; Qinhuangdao 066004
2.Department of Environmental & Chemical Engineering; Yanshan University; Qinhuangdao 066004
3.Hebei Normal University of Science & Technology; Qinhuangdao 066004
4.Department of Environmental Engineering; Environmental Management College of China; Qinhuangdao 066004
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Abstract  

In order to realize the dechromization of copper alloy in HCl solution, the effect of the sample state on dechromization of Cu-Cr alloy was studied by means of metallographic observation, X-ray diffractometer(XRD), scanning electron microscope(SEM/EDX), and X-ray fluorescence spectrometer, and the mechanism was also analyzed. The results showed that the bigger the sample deformation and surface roughness, the shorter the incubation time of dechromization, and the lower the concentration and temperature of solution for the dechromization, and it is conducive to dechromization of Cu-Cr alloy. As a result, the deformation can increase the dechromization rate, and decrease the compactibility of the microstructure of the dechromization layer, but the surface roughness does not obviously affect the dechromization rate.

Key words:  Cu-Cr alloy      dechromization corrosion      surface roughness      deformation     
Received:  06 March 2007     
ZTFLH: 

TG172.82

 
Corresponding Authors:  LIU Yuwen     E-mail:  ljh10@ysu.edu.cn

Cite this article: 

FAN Liru LIU Yuwen WANG Kuan LI Yuan SUN Qina. EFFECT OF THE SAMPLE STATE ON DECHROMIZATION OF Cu-Cr ALLOY. J Chin Soc Corr Pro, 2009, 29(1): 15-18.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2009/V29/I1/15

[1] Abbas M I. Effects of temperature on dezincification and electro-chemical behavior of 70-30 brass in sulphuric acid [J]. Br. Corros. J.,1991,26(4):273-278
[2] Beccaria A M,Crousier J. Dealloying of Cu-Ni alloys in natural sea water[J]. Br. Corros.J.,1989,24(1):49-52
[3] Newman R C,Shahrabi T. Dezincification of alpha-brass in crevices-technical note[J].Corrosion,1993,49(1): 60-62
[4] Lv H B,Li Y,Wang F H. Corrosion characteristics of Cu-20Zr alloy in hydrochloric acid solution[J]. J. Chin. Soc. Corros. Prot.,2006,26(2):75-79
(吕海波,李瑛,王福会.Cu-20Zr合金在盐酸溶液中的脱合金腐蚀历程[J].中国腐蚀与防护学报,2006,26(2):75-79)
[5] Yu H,Dong S Y,Huang G S. Corrosion behavior of Al-bronze in 3.5% NaCI solution[J].J. Chin. Soc. Corros. Prot.,2003,23(6):345-349
 (于辉,董飒英,黄国胜.铝青铜在3.5%NaCl溶液中的脱成份腐蚀行为[J].中国腐蚀与防护学报,2003,23(6):345-349)
[6] Han Z,He Y F,Lin H C,et al. Study on dealloying corrosion of QAl-9-2 alloy in 3.5%NaCl solution[J]. Acta Metall. Sin.,2000,36(5):521-524
 (韩忠,何毓璠,林海潮等. QA1-9-2合金在3.5%NaC1溶液中脱合金腐蚀研 究[J].金属学报,2000,36(5):521-524)
[7] Li C J. Study on kinetics of low carbon steel hydrochloric acid corrosion[J]. J.Daqing Pet. Inst.,1999,23(3):28-30
 (李春杰. 盐酸腐蚀低碳钢的动力学研究[J].大庆石油学院学报,1999,23(3):28-30)
[8] Li C.Metallograph Theory[M]. Harbin: Harbin Institute of Technology Press,1996:212
 (李超. 金属学原理[M]. 哈尔滨:哈尔滨工业大学出版社,1996:212)
[9] Zhu X L,Lin L Y,Lei T Q. Corrosion resistance of deformed Cu-Ni alloy in seawater[J]. Rare Met.,1997,16(1):17-19
 (朱小龙,林乐耘,雷廷权. 形变Cu-Ni合金在海水中的腐蚀性能[J]. 稀有金属,1997,16(1):17-19)
[10] Zhu X L,Lin L Y,Xu J,et al.Effect of deformation on corrosion behaviors of 70Cu-30Ni alloy[J].Chin. J. Nonferrous Met.,1997,7(2):82-84
 (朱小龙,林乐耘,徐杰等. 形变对70Cu-30Ni合金腐蚀行为的影响[J].中国有色金属学报,1997,7(2):82-84)
[11] Cao L Y,You X Q,Wang L M. The Influences of plastic deformation and grain size upon corrosion property of decorative copper alloys[J]. J. Liaoning Inst. Technol.,1994,14(2):10-14 }
(曹丽云,由向群,王丽梅.塑性变形及晶粒度对装饰合金腐蚀性能的影响[J].辽宁工学院学报,1994,14(2):10-14)
[12] Cui K. Iron and Steel Materials & Nonferrous Metals[M]. Beijing: China Machine Press, 1986
 (崔崑.钢铁材料及有色金属材料[M]. 北京: 机械工业出版社,1986)

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