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Journal of Chinese Society for Corrosion and protection  2025, Vol. 45 Issue (6): 1669-1678    DOI: 10.11902/1005.4537.2025.035
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Effect of Pressure Load and Friction Frequency on Wear Corrosion Behavior of 7075 Al-alloy
LI Zanlong, YAN Qing, MAN Cheng()
School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
Cite this article: 

LI Zanlong, YAN Qing, MAN Cheng. Effect of Pressure Load and Friction Frequency on Wear Corrosion Behavior of 7075 Al-alloy. Journal of Chinese Society for Corrosion and protection, 2025, 45(6): 1669-1678.

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Abstract  

7075 Al-alloy is subjected to the dual effects of wear and corrosion in marine environment, resulting in long-term accumulation failure, which causes a serious threat to the safety and efficiency of offshore operations. However, the mechanism by which wear and corrosion affect the corrosion behavior of 7075 Al-alloy is still unclear. Hence, the wear and corrosion behavior of 7075 Al-alloy was studied in conditions of varying pressure load and friction frequency in terms of the coefficient of friction (COF), open circuit potential and potentiodynamic polarization, meanwhile the s morphology and composition of the friction-wear scars was examined by SEM image and the results of EDS. The main conclusions are as follows: COF values increase to different degrees under different friction frequencies and different pressure loads. Compared to static corrosion environment, the current density of 7075 Al-alloy under friction condition increases significantly by 2-3 orders of magnitude. When the friction force is relatively low (5 N-0.01 Hz and 5 N-0.10 Hz), the mechanism is abrasive wear; when the friction force is relatively high, it is adhesive wear, which is manifested as a large-particle tearing morphology. Therefore, the loss of materials caused by wear and corrosion is not a simple superposition of static corrosion and mechanical wear.

Key words:  7075 Al-alloy      wear corrosion      wear mechanism      interaction     
Received:  13 February 2025      32134.14.1005.4537.2025.035
ZTFLH:  TG174  
Fund: Shandong Provincial Colleges and Universities Youth Innovation Team Plan(2022KJ055)
Corresponding Authors:  MAN Cheng, E-mail: mancheng@ouc.edu.cn

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2025.035     OR     https://www.jcscp.org/EN/Y2025/V45/I6/1669

Fig.1  Schematic diagram of tribocorrosion device
Fig.2  COF (a, b) and OCP (c, d) curves of 7075 Al-alloy during tribocorrosion at different frequencies (a, c) and applied loads (b, d)
Fig.3  Potentiodynamic polarization curves (a, b) and fitting date (c, d) of 7075 Al-alloy during tribo-corrosion at different frequencies (a, c) and applied loads (b, d)
f / HzLoad / NEcorr vs. SCE / VEpit vs. SCE / VIcorr / μA·cm-2
00-0.71-0.702.24
0.015-0.89-0.770.69
0.105-1.14-0.772.88
0.255-1.18-0.752.24
0.505-1.19-0.768.71
0.755-1.20-0.7412.59
1.005-1.19-0.7314.45
1.0010-1.21-0.7517.78
1.0020-1.23-0.7431.62
1.0030-1.24-0.7440.74
1.0040-1.24-0.7356.23
Table 1  Fitting parameters of potentiodynamic polarization curves of 7075 Al-alloy
Fig.4  3D morphologies of the wear tracks of 7075 Al-alloy after tribocorrosion at different frequencies and loads: (a) 0.01 Hz, 5 N, (b) 0.05 Hz, 5N, (c) 0.10 Hz, 5 N, (d) 0.50 Hz, 5 N, (e) 0.75 Hz, 5 N, (f) 1.00 Hz, 5N, (g) 1.00 Hz, 10 N, (h) 1.00 Hz, 20 N, (i) 1.00 Hz, 30 N, (j) 1.00 Hz, 40 N
Fig.5  Cross-section profiles of the wear tracks (a, b) and wear volumes (c, d) of 7075 Al-alloy after tribo-corrosion at different frequencies (a, c) and applied loads (b, d)
Fig.6  SEM images of the wear tracks of 7075 Al-alloy after tribocorrosion at different frequencies and loads: (a) 0.01 Hz, 5 N, (b) 0.05 Hz, 5 N, (c) 0.10 Hz, 5 N, (d) 0.50 Hz, 5 N, (e) 0.75 Hz, 5N, (f) 1.00 Hz, 5 N, (g) 1.00 Hz, 10 N, (h) 1.00 Hz, 20 N, (i) 1.00 Hz, 30 N, (j) 1.00 Hz, 40 N
ElementOAlSiClMnFeCuZnMg
Point Ⅰ49.9641.950.614.060.000.460.241.211.04
Point Ⅱ58.5335.030.103.480.000.000.291.071.50
Point Ⅲ2.6787.770.110.050.240.001.385.622.14
Point Ⅳ26.4164.860.051.290.090.001.034.691.59
Table 2  EDS results of the compositions of the four marked points in Fig.6
Fig.7  Loss ratios of various wear components for 7075 Al-alloy after tribo-corrosion conditions at different frequencies (a, b) and applied loads (c, d) (Fig.7b and Fig.7d are enlarged views of the red dashed boxes in Fig.7a and Fig.7b, respectively)
f / HzLoad / NT / mm3W0 / mm3C0 / mm3ΔWc / mm3ΔCw / mm3W/CΔWc/W0
0.0150.0100.012.70 × 10-70.011.00 × 10-7> 10< 1
0.1050.0400.022.70 × 10-70.012.10 × 10-6> 10< 1
0.2550.1010.102.70 × 10-70.014.80 × 10-6> 10< 1
0.5050.2410.222.70 × 10-70.025.90 × 10-6> 10< 1
0.7550.3310.302.70 × 10-70.038.00 × 10-6> 10< 1
1.0050.4610.432.70 × 10-70.031.20 × 10-5> 10< 1
1.00100.8810.842.70 × 10-70.041.80 × 10-5> 10< 1
1.00202.2012.122.70 × 10-70.082.90 × 10-5> 10< 1
1.00302.3612.312.70 × 10-70.063.20 × 10-5> 10< 1
1.00402.3212.302.70 × 10-70.024.00 × 10-5> 10< 1
Table 3  Calculated values of various wear components under the different tribocorrosion conditions
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