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| Design and Performance of Acrylic Acid-motherwort Dregs Composite Carbon Dots for Fluorescent Scale Inhibitor |
ZHANG Hongjiang1( ), CHEN Jiaqi2, XIE Weiwei2, LIU Zhongxuan2, DONG Sheying2 |
1.North China Electric Power Research Institute Co., Ltd., Beijing 100045, China
2.School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an 710311, China |
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Cite this article:
ZHANG Hongjiang, CHEN Jiaqi, XIE Weiwei, LIU Zhongxuan, DONG Sheying. Design and Performance of Acrylic Acid-motherwort Dregs Composite Carbon Dots for Fluorescent Scale Inhibitor. Journal of Chinese Society for Corrosion and protection, 2025, 45(3): 812-820.
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Abstract In recent years, the fluorescence detection technology has become the main methods of on-line detection for scale inhibitors. Then, fluorescence-type scale inhibitors play a key role in the above inspection, and its research work is need urgently. Herein, novel composite carbon dots (AA-CDM) of acrylic acid-motherwort dregs, which was synthesized using a one-step hydrothermal method with motherwort dregs and acrylic acid as raw materials. Then, the rationality of AA-CDM synthesis process was confirmed by infrared spectrum and X-ray photoelectron spectroscopy. In the anti-scaling aspect, the results of scale inhibition test showed that the AA-CDM presents remarkably enhanced scale inhibition efficiency, which is attributed to the introduction of acrylic acid into the motherwort-dregs-based. The inhibition efficiency of AA-CDM in low concentration (5 mg·L-1) for CaSO4-type scale was close to 100%, and what is more, which may be retained above 95% origin level, even in 45 h after the first use. Besides, the relevant anti-scaling mechanism of AA-CDM was analyzed, the outcomes of XRD, XPS, and ultraviolet differential spectroscopy exhibit that AA-CDM has the chelating solubilization ability, which can inhibit the normal growth of CaSO4 scale. Meanwhile, the fluorescence intensity of AA-CDM showed a linear correlation with its concentration (R2 = 0.999), and the material presents has also good in thermal stability of fluorescence. Overall, the AA-CDM is suitable for most circulating water systems, and remains design method to get a novel fluorescent scale inhibitor.
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Received: 28 May 2024
32134.14.1005.4537.2024.167
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| Fund: North China Electric Power Research Institute of Chemistry and Environmental Protection(20230744) |
Corresponding Authors:
ZHANG Hongjiang, E-mail: 416228638@qq.com
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