Oxidation Behavior of Stainless Steel 1Cr11Ni2W2MoV in a Simulated Kerosene Combustion Environment

doi:10.11902/1005.4537.2019.024

Journal of Chinese Society for Corrosion and protection

2020, Vol. 40

Issue (4): 358-366 DOI: 10.11902/1005.4537.2019.024

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Oxidation Behavior of Stainless Steel 1Cr11Ni2W2MoV in a Simulated Kerosene Combustion Environment

XIE Dongbai¹(

), HONG Hao², WANG Wen³, PENG Xiao¹, DUO Shuwang²

1. School of Material Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China
2. Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, China
3. Laboratory of Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

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Abstract

Metallic materials exposed to fire scenes are usually subjected to high temperature oxidation, of which the atmosphere composition and temperature have been considered as vital parameters. In this study, the high temperature oxidation behavior of 1Cr11Ni2W2MoV stainless steel in air and simulated kerosene-combustion atmosphere at 600, 700 and 800 ℃ were studied by means of visual analysis and micro-structural observation of the formed oxide scale. The results show that the 1Cr11Ni2W2MoV possessed good oxidation resistance and the scales primarily remained continuous and well adherent to the substrate in air. Whilst, the presence of kerosene combustion products apparently increased the consumption of Cr element, reduced the adhesion of oxide scale and hence decreased the oxidation resistance of the steel. Additionally, the combustion products of kerosene resulted in the formation of nodular oxides in the formed scale. Therefore, the combustion of kerosene in fire scene could increase the oxidation rate of 1Cr11Ni2W2MoV, which are expected to offer complementary insight into reconstruction of fire scene.

Key words: combustion environment fire investigation 1Cr11Ni2W2MoV oxide high temperature oxidation

Received: 14 February 2019

ZTFLH:

TG172

Fund: Startup Foundation for Doctors of Nanchang Hangkong University, Key Laboratory of Impression Evidence Examination and Identification Technology, Ministry of Public Security, China (2019) and Open-fund Project of Jiangxi Key Laboratory of Materials Surface Engineering(KFGJ19009)

Corresponding Authors: XIE Dongbai E-mail: dbxie@aliyun.com

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	Dongbai XIE
	Hao HONG
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	Xiao PENG
	Shuwang DUO

Cite this article:

XIE Dongbai, HONG Hao, WANG Wen, PENG Xiao, DUO Shuwang. Oxidation Behavior of Stainless Steel 1Cr11Ni2W2MoV in a Simulated Kerosene Combustion Environment. Journal of Chinese Society for Corrosion and protection, 2020, 40(4): 358-366.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2019.024 OR https://www.jcscp.org/EN/Y2020/V40/I4/358

Fig.1 Tube furnace setup for oxidation experiment in air and simulated kerosene combustion environments (the arrow along the furnace shows the flow direction of reaction gas from combustion furnace to reaction furnace)

Fig.2 Temperature plots in the reaction furnace under air (a) and air-kerosene (b) atmospheres

Fig.3 Surface morphologies of the samples after oxidation at 600 ℃ in air (a~e) and in air-kerosene (f~i) for 0 min (a), 15 min (b, f), 30 min (c, g), 45 min (d, h) and 1 h (e, i)

Fig.4 Surface morphologies of the samples after oxidation at 800 ℃ in air (a~e) and in air-kerosene (f~h) for 0 min (a), 15 min (b, f), 30 min (c, g), 45 min (d, h) and 1 h (e) (the linishing marks on samples' surface formed when the samples were picked up by using a tweezer)

Fig.5 AFM images of 1Cr11Ni2W2MoV steel before (a) and after oxidation in air (b) and air-kerosene (c) at 600 ℃ for 30 min

Fig.6 AFM images of 1Cr11Ni2W2MoV samples after oxidation in air (a) and air-kerosene (b) at 800 ℃for 30 min

Fig.7 AFM images of 1Cr11Ni2W2MoV samples after oxidation at 600 ℃ (a), 700 ℃ (b) and 800 ℃ (c) in air-kerosene for 1 h

Fig.8 SEM images of 1Cr11Ni2W2MoV samples after oxidation in air (a, b) and air-kerosene (c, d) at 600 ℃ for 1 h

Fig.9 SEM images of 1Cr11Ni2W2MoV samples after oxidation in air (a, b) and air-kerosene (c,d) at 800 ℃ for 1 h

Fig.10 SEM cross-sectional images of 1Cr11Ni2W2MoV samples after oxidation in air (a) and air-keros-ene (b) at 600 ℃ for 1 h

Fig.11 SEM cross-sectional images of 1Cr11Ni2W2MoV samples after oxidation in air (a) and air-kerosene (b) at 700 ℃ for 1 h and the magnified image of area I in Fig.11b (c)

Fig.12 SEM cross-sectional images of 1Cr11Ni2W2MoV samples after oxidation in air (a) and air-kerosene (b) at 800 ℃ for 30 min and the magnified image of area I in Fig.12b (c)

Fig.13 XRD patterns of 1Cr11Ni2W2MoV samples after oxidation in air and air-kerosene at 600 ℃ for 1 h (a), and at 800 ℃for 15 min (b) and 1 h (c)

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