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STUDY ON THE PROTECTION POTENTIALAGAINST PITTING CORROSION OF A3 STEEL AND 304 SS |
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北京化工大学材料科学与工程学院 |
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Abstract Two methodssimulated occluded cell and simulated occluded solutionhave been developed to determine the protection potential aga inst pitting of A3 steel and 0Cr18Ni9 stainless steel.They are based on the theo ry that the pitting protection potential(EP) is actually the transition po tential of the direction of current between the occluded cell and the external s urface(ET).The ET of 304 SS in 0.5 mol·L-1 NaCl solution is in the range of 220 mV to 440 mV(SCE), the ET of A3 steel in 0.01 mol ·L-1 NaCl solution(pH=12) is in the range of 390~670 mV, the lowest of which can be considered as cathode protection potential(EP).The E P of 304 SS determined with “cyclic” potentiodynamic polarization method is included in the ET with above methods.As for electrochemical protection ag ainst pitting, if the potential of the external surface is controlled below the EP,the activepassive transition will occur inside the occluded cell, so the pitting will be stifled.
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Received: 03 January 2000
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