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J Chin Soc Corr Pro  2005, Vol. 25 Issue (5): 295-298     DOI:
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EFFECT OF CATHODIC POLARIZATION ON CHEMICAL AND ELECTROCHEMICAL STATES INSIDE OCCLUDED CELLS OF LOCALIZED CORROSION OF CAST IRON IN ALKALINE SOLUTION
Chunchun Xv;Lijie Yue;Weizhen Ouyang
北京化工大学材料科学与工程学院
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Abstract  A simulated galvanostatic occluded cell was used to investigate the effect of cathodic polarization on chemical and electrochemical states inside occluded cell (OC) of localized corrosion for cast iron in alkaline solution.It has been found that as the cathodic current passes through the cell,the pH value of the OC solution rises with prolonging of time and rising of current density;the rate of Cl- migrating out from the OC also rises with prolonging of time and rising of current density.Because of Cl- migrating out fro m OC and OH- immigrating into OC,the localized corrosion was retarded.Passing cathodic polarization in alkaline solution can make Cl- migrating more quickly ,it is more efficiency than the cast iron dipping in alkaline solution(no cathod ic polarization).
Key words:  alkaline solution       cast iron      occluded cell      cathodic polarization      
Received:  26 March 2004     
ZTFLH:  TG174.41  
Corresponding Authors:  Chunchun Xv     E-mail:  chunchunxu@163.com

Cite this article: 

Chunchun Xv; Lijie Yue; Weizhen Ouyang. EFFECT OF CATHODIC POLARIZATION ON CHEMICAL AND ELECTROCHEMICAL STATES INSIDE OCCLUDED CELLS OF LOCALIZED CORROSION OF CAST IRON IN ALKALINE SOLUTION. J Chin Soc Corr Pro, 2005, 25(5): 295-298 .

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2005/V25/I5/295

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