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Surface Activity of HR-2 Stainless Steel in Acid Solution with SECM |
CHEN Zhen1, YU Qiang1, LIAO Denghui2,GUO Zhongcheng2, WU Jian2, LUO Zhishan1 |
1. Faculty of Science, Kunming University of Science and Technology, Kunming 650093, China;
2. Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China |
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Abstract By surface scanning technology and linear scanning technology with SECM, which have a micrometer pixel, corrosion behavior of HR-2 stainless steel in 0.5 mol/L H2SO4+0.1 mol/L NaCl solution was studied. The results show that: open circuit potential, activation potential, and passivation potential are -0.4 V, -0.23 V, 0.0 V ~ 0.8 V relatively. The maximum current of probe is 9.5 nA when substrate current is open circuit potential 35.2nA, when substrate current is activation potential. When passive film formed on the substrate, the current of probe largely decreased. H2 was obtained when current of probe is -0.2 V, Fe2+ was obtained when current of probe is 0.6 V. It is also observed that the proper distance between probe and substrate is 20 μm, and best concentration of the corrosion inhibition (sulfocarbamide) is 0.75 mmol/L.
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[1] Zhang X Y, Han E H, Li H X. Estimation of the corrosion losses by the acidic rain in China [J]. J. Chin. Soc. Corros. Prot., 2002, 22(5):316-319(张学元,韩恩厚,李洪锡. 中国的酸雨对材料腐蚀的经济损失估算 [J] .中国腐蚀与防护学报, 2002, 22(5): 316-319)[2] Bard A J, Mirkin M V. Scanning Electrochmical Microscopy [M]. New York, Marcel Dekker, Inc, 2001[3] ShaoY H. Recent advances in scanning electrochemical microscopy [J]. Chin. J. Analy. Chem., 1999, 27(11): 1348-1355(邵元华. 扫描电化学显微镜及其最新进展 [J]. 分析化学评述与进展, 1999, 27(11): 1348-1355)[4] Cao J, Shao L W, Zhang T, et al. Roles of zinc phosphate on the corrosion of the scratched epoxy coating [J]. J. Chin. Soc. Corros. Prot., 2009, 29(6): 437-441(曹佳, 邵立微, 张涛等. 磷酸锌对环氧涂层破损处金属的缓蚀作用 [J]. 中国腐蚀与防护学报, 2009, 29(6): 437-441)[5] Wang L W, Li X G, Du C W, et al. Recent advances in local electrochemical measurement techniques and applications in corrosion research [J]. J.Chin. Soc. Corros. Prot., 2010, 30(6): 498-503(王力伟, 李晓刚, 杜翠薇等. 微区电化学测量技术进展及在腐蚀领域的应用 [J]. 中国腐蚀与防护学报, 2010, 30(6) 498-503)[6] Williams M E, Stevenson K J, Massari A M ,et al. Imaging size-selective permeation through micropatterned thin films using scanning electrochemical microscopy [J]. Anal. Chem., 2000, 72 (14):3122-3128[7] Uitto, Olivia D, Whitem, et al. Scanning electrochemical microscopy of membrane-transport in the reverse imaging mode [J]. Anal. Chem., 2001, 73(3): 533-539[8] Mirkin M V, Fan F F, Bard A J. Direct electrochemical measurements inside a 2000 angstrom thick polymer film by scanning electrochemical microscopy [J]. Science, 1992, 257: 364-366[9] Wittstock G, Schuhmann W. Formation and imaging of microscopic enzymatically active spots on an alkanethiolate-covered gold electrode by scanning electrochemical microscopy [J]. Anal. Chem., 1997, 69(24): 5059-5066[10] Yasukawa T, Kaya T, Matsue T. Dual imaging of topography and photosynthetic activity of a single protoplast by scanning electrochemical microscopy [J]. Anal. Chem., 1999, 71(20): 4637-4641[11] S11iku H, Matsue T, Uchida I. Detection of microspotted carcinoembryonic antigen on a glass substrate by scanning electrochemical microscopy [J]. Anal. Chem., 1996, 68(7): 1276-1278[12] Turyan I, Matsue T, Mandler D. Patterning and characterization of surfaces with organic and biological molecules by the scanning electrochemical microscope [J]. Anal. Chem., 2000, 72(15): 3431-3435[13] Cai C, Liu B, Mirkin M V. Scanning electrochemical microscopy of living cells.3.rhodobacter sphaeroides [J]. Anal. Chem., 2002, 74(1): 114-119[14] Seegmiller J C, Buttry D A. A SECM study of heterogeneous redox activity at Al 2024 surfaces [J]. J. Electrochem. Soc., 2003, 150(9): 413-418 |
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