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Abstract The corrosion-inhibiting abilities of a series of ringsubstituted benzonitriles were investigated. As in the case of benzene-acetonitriles, chemisorption is probably the mechanism of the corrosion-inhibiting effects.Introducing electtondonating groups in the para-position increases the corrosion-inhibiting ability, while introducing of electron-withdrown groups in the para-position decreases the corrosion inhibiting ability, when a substituent is positioned in o, m or P positions,both elec tronic and steric effects of the substituent affect the corrosioninhibiting ability. Besides, synergistic effect was observed when P-chlorobenzonitrile was used together with anionic or cationic dispersion agents.
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Received: 25 June 1987
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[1] Thomposon, C. D.; Mackerman, N., Corros. Sci. 13(5) , 317~24(1973) [2] Carassiti, V., et al., Ann, Univ. Ferrara, Sez, 5, 525~37(1971) .(C. A., 75, 29184 x) [3] Costain, W.; Terry, B. W. H., Ger. Offen. 2, 311, 171(1973) .(C. A., 80, 29709 a) [4] 邱玉珠等,中国腐蚀与防护学报,5(1) ,72~78(1985) [5] Olah, G. A., et al., Synthesis, 112(1979) [6] Luecke, J., et at., Chimia, 25, 94(1971) [7] Heilleron, I., etal., Dictionary of Organic Compounds, Fourth Edition, London(1965) [8] Sadtler Research Lal, Inc., The Sadtler Standard Spectra. Standard Infrared Grating Spectra 20847. [9] 傅献彩等编,物理化学(下册),人民教育出版社,206~7(1979年修订本) [10] 理论电化学,吴仲达等译,高等教育出版社.280(1984) |
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