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J Chin Soc Corr Pro  1990, Vol. 10 Issue (3): 239-244    DOI:
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ELECTROCHEMICAL BEHAVIOR AND SURFACE COMPOSITION OF FERRITIC STAINLESS STEELS CONTAINING Cu AND Nb IN SULFURIC ACID SOLUTION
Guo Jajiu (Beijing University of Science and Techn ology;Chjna)Masahiro Seo Norio Sato (Hokkaido University;Japan)
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Abstract  Electrochemical behavior and surface composition of ferritic stain- less steels containing Cu and Nb in 1.0 mol.din~(-3) sulfuric acid solution have been investigated to evaluate the effects of alloying elements Cu and Nb on the corrosion resistance of ferritic stainless steel.The ac- tive dissolution current density of copper added steel is suppressed significantly because of the surface enrichment of metallic copper. From the measurements of the reactivation potential by a cathodic potential sweep of the passivated steel,it is found that the copper addition has a detrimental effect on the passivity.On the other hand, the addition of niobium improved the passivity of ferritic stainless steel. Auger Spectroscopy revealed that the niobium existed in the inner layer of passive film.Therefore with both niobium and copper added,the ferritic stainless steel shows excellent corrosion resistance,because active disolution is decelerated by copper addition and because passive film is improved by niobium addition.
Received:  25 June 1990     
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Guo Jajiu (Beijing University of Science and Techn ology;Chjna)Masahiro Seo Norio Sato (Hokkaido University;Japan). ELECTROCHEMICAL BEHAVIOR AND SURFACE COMPOSITION OF FERRITIC STAINLESS STEELS CONTAINING Cu AND Nb IN SULFURIC ACID SOLUTION. J Chin Soc Corr Pro, 1990, 10(3): 239-244.

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y1990/V10/I3/239

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