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| Preparation and Antimicrobial Properties of a Novel Cu-containing Ti-alloy |
DENG Yan1, PENG Zipiao2, LIU Yichao3,4, ZHONG Xiankang5( ) |
1 College of Petroleum and Natural Gas Engineering, Southwest Petroleum University, Chengdu 610500, China
2 Supervision Center, PetroChina Tarim Oilfield Branch, Korla 841000, China
3 Safety, Environmental Protection and Quality Supervision and Inspection Research Institute of Sichuan Qing Drilling and Exploration Engineering Co. Ltd. , Deyang 618300, China
4 Sichuan Cote Testing Technology Co. Ltd. , Deyang 618300, China
5 College of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China |
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Cite this article:
DENG Yan, PENG Zipiao, LIU Yichao, ZHONG Xiankang. Preparation and Antimicrobial Properties of a Novel Cu-containing Ti-alloy. Journal of Chinese Society for Corrosion and protection, 2025, 45(6): 1649-1658.
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Abstract Currently, oil well tubing and surface pipelines are facing severe risks of microbial corrosion (MIC). Microorganisms can multiply in fracturing fluids, drilling muds, and formation water, resulting in significant corrosion and clogging of oil well tubing and surface pipelines, and other accidents, which seriously affect oil and gas production and safety. Ti-alloy has the advantages of corrosion resistance and high strength, but its antimicrobial properties require further investigation. This article, a novel Cu-containing Ti-alloy TC18-0.5Cu was made by vacuum arc melting, which then subjected to 800 oC solid solution treatment (ST800), 800 oC SS treatment plus 580 oC aging treatments (ST800AG580), and 800 oC SS treatment plus 620 oC aging treatment, respectively. Futher, the antimicrobial performance of the three alloys was assessed in sulfate-reducing bacteria (SRB) containing artificial formation waters, meanwhile the growth of sulfate-reducing bacteria (SRB) was analyzed by surface morphology and biofilm thickness, and the bactericidal rate of the Ti-alloys was calculated based on the results of the confocal microscope shots. The results showed that the sterilization rate of the three copper-containing Ti-alloys with different heat treatments could reach more than 75%, suggesting that the heat treatment processes had no significant effect on their sterilization effect. The antimicrobial property of the copper-containing Ti-alloy is due to the fact that the Cu in the alloys is dissolved in the corrosive environment, and the Cu ions destroy the bacterial membrane of bacteria such as SRB, thus inhibiting the growth of bacteria. Furthermore, electrochemical tests revealed that the addition of a small amount of copper, combined with a suitable heat treatment process, also improved the corrosion resistance of the alloy.
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Received: 08 January 2025
32134.14.1005.4537.2025.013
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| Fund: CNPC Innovation Found(2021DQ02-0504) |
Corresponding Authors:
ZHONG Xiankang, E-mail: zhongxk@yeah.net
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