N-(羟甲基)丙烯酰胺(NMA)改性丙烯酸树脂的合成及其防污性能研究

doi:10.11902/1005.4537.2024.115

中国腐蚀与防护学报

2025, Vol. 45

Issue (3): 747-756 CSTR: 32134.14.1005.4537.2024.115 DOI: 10.11902/1005.4537.2024.115

研究报告

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N-(羟甲基)丙烯酰胺(NMA)改性丙烯酸树脂的合成及其防污性能研究

田秋梅, 倪春花, 骆云鹏, 王言建, 许豪, 李霞, 于良民, 闫雪峰(

)

中国海洋大学海洋化学理论与工程技术教育部重点实验室青岛 266100

Preparation and Antifouling Properties of N-Methylol Acrylamide (NMA)-Modified Acrylic Resins

TIAN Qiumei, NI Chunhua, LUO Yunpeng, WANG Yanjian, XU Hao, LI Xia, YU Liangmin, YAN Xuefeng(

)

Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education, Ocean University of China, Qingdao 266100, China

引用本文:

田秋梅, 倪春花, 骆云鹏, 王言建, 许豪, 李霞, 于良民, 闫雪峰. N-(羟甲基)丙烯酰胺(NMA)改性丙烯酸树脂的合成及其防污性能研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 747-756.
Qiumei TIAN, Chunhua NI, Yunpeng LUO, Yanjian WANG, Hao XU, Xia LI, Liangmin YU, Xuefeng YAN. Preparation and Antifouling Properties of N-Methylol Acrylamide (NMA)-Modified Acrylic Resins[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(3): 747-756.

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摘要:

将N-(羟甲基)丙烯酰胺(NMA)引入丙烯酸自抛光树脂体系制备了具有自交联特性和防污性能的RZn-NMA-X自更新涂层。通过将自抛光树脂与亲水性交联网络相结合，在60 d的静态泡水实验中，RZn-NMA-X涂层在海水中展现出稳定的水解速率和稳定的成膜表面。实验室生物测定和150 d海洋现场测试表明，RZn-NMA-X聚合物具有良好的防污性能，最佳含量为5%NMA。研究表明，适量NMA的引入不仅增强了涂层防污性能，而且较好的表面特性为其逐步抛光，抵抗生物污损提供保障，有利于增加海洋设备服役时长。本工作所提制备方法简单，原料廉价易得，可用于防污应用的规模化生产。

关键词 ：丙烯酸树脂, 自抛光, 自交联, 防污, N-(羟甲基)丙烯酰胺(NMA)

Abstract：

A novel self-renewable coating RZn-NMA-X with self-crosslinking properties and antifouling performance was prepared by introducing N-Methylol acrylamide (NMA) into a self-polishing acrylic resin. The coating formed by the combination of a self-polishing resin with a hydrophilic crosslinking network referred to as RZn-NMA-X, exhibited a stable hydrolysis rate and stable film-forming surface in seawater in a 60 d static soaking test. The laboratory bioassay and 150 d marine field test showed that the RZn-NMA-X polymer has good antifouling properties with an optimal content of 5%NMA. In conclusion, the incorporation of an appropriate amount of NMA not only enhances the antifouling performance of the coating, but also provides assurance for its gradual polishing and resistance to biofouling due to its favorable surface characteristics, which is beneficial for enhancing the longevity of marine antifouling in coating applications. The preparation method suggested in this study is straightforward, and the raw materials are affordable and readily available, making it suitable for large-scale production in antifouling applications.

Key words： acrylic resin self-polishing self-crosslinking antifouling N-Methylol acrylamide (NMA)

收稿日期: 2024-04-07 32134.14.1005.4537.2024.115

ZTFLH:

TG174

基金资助:国家自然科学基金(U22A20112);海南省自然科学基金(522CXTD520);山东省重点研发项目(2022CXGC020401)

通讯作者: 闫雪峰，E-mail：yanxuefeng@ouc.edu.cn，研究方向为海洋防护材料

Corresponding author: YAN Xuefeng, E-mail: yanxuefeng@ouc.edu.cn

作者简介: 田秋梅，女，1997年生，硕士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2024.115 或 https://www.jcscp.org/CN/Y2025/V45/I3/747

图1 RZn-NMA-X聚合物的合成路线和合成工艺

表1 RZn-NMA-X聚合物的实验配方

图2 N. closterium的波长扫描图和标准曲线

表2 RZn-NMA-X树脂的基本指标

图3 含NMA的丙烯酸聚合物的FTIR光谱

图4 RZn-NMA-X聚合物涂层的附着力

图5 RZn-NMA-X聚合物涂层的质量损失随浸泡时间的变化和在海水中浸泡50 d前后的接触角变化

图6 RZn-NMA-X聚合物涂层浸泡不同时间后的表面数码图像，激光共聚焦形貌图，激光共聚焦三维形貌及粗糙度变化

图7 RZn-NMA-X聚合物涂层对假交替单胞菌的抗菌作用和抗菌率

图8 RZn-NMA-X对N. closterium的生长抑制曲线

图9 RZn-NMA-X聚合物涂层在胶州湾海域浸泡30~150 d后的污损生物附着情况

表3 测试面板浸泡150 d的防污打分结果

图10 RZn-NMA-X聚合物涂层的防污机理

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