论不可逆电极过程的法拉第阻抗等效电路类型

中国腐蚀与防护学报

1990, Vol. 10

Issue (2): 159-170

研究报告

本期目录 | 过刊浏览

论不可逆电极过程的法拉第阻抗等效电路类型

曹楚南

中国科学院腐蚀科学开放研究实验室

ON THE EQUIVALENT CIRCUITS OF FARADAIC IMPEDANCE OF IRREVERSIBLE ELECTRODE REACTIONS

Gao Chu'nan (Corrosion Science Laboratory; Institute of Corrosion and Protection of Metals; Aeademia Sinica)

全文: PDF(1251 KB)

摘要: 根据定态过程的稳定性条件和线性系统的性质,对于扩散过程的影响可以忽略的不可逆电极过程,可以导出恒电位条件下的法拉第导纳方程式,并可据以讨论可能的法拉第阻抗的等效电路。本文讨论了除电极电位E外还有1个和2个状态变量的电极过程的情况。

Abstract：Based on the stability conditions of steady state and the characteristics of linear systems, the equations of fardaic admittance measured under potentiostatic condition can be derived and the equivalent circuits of faradaic impedance can be discussed for irreversible electrode reactions where the diffusion effect can be ignored. The possible equivalent circuits for faradaic processes with one and two state variables besides electrode potential are discussed.

收稿日期: 1990-04-25

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引用本文:

曹楚南. 论不可逆电极过程的法拉第阻抗等效电路类型[J]. 中国腐蚀与防护学报, 1990, 10(2): 159-170.
. ON THE EQUIVALENT CIRCUITS OF FARADAIC IMPEDANCE OF IRREVERSIBLE ELECTRODE REACTIONS. J Chin Soc Corr Pro, 1990, 10(2): 159-170.

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https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y1990/V10/I2/159

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[7] 曹楚南,论不可逆电极过程的阻抗平面图的类型(Ⅱ),中国科学院腐蚀科学开放研究实验室一九八八年年报,86～99页(1988)
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