含噻二唑季铵盐表面活性剂的合成及缓蚀杀菌性能研究

doi:10.11902/1005.4537.2021.082

中国腐蚀与防护学报

2022, Vol. 42

Issue (1): 51-59 DOI: 10.11902/1005.4537.2021.082

研究报告

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含噻二唑季铵盐表面活性剂的合成及缓蚀杀菌性能研究

朱海林(

), 陆小猛, 李晓芬, 王俊霞, 刘建华, 冯丽, 马雪梅, 胡志勇

中北大学化学工程与技术学院太原 030051

Synthesis, Corrosion Inhibition and Bactericidal Performance of an Ammonium Salt Surfactant Containing Thiadiazole

ZHU Hailin(

), LU Xiaomeng, LI Xiaofen, WANG Junxia, LIU Jianhua, FENG Li, MA Xuemei, HU Zhiyong

School of Chemical Engineering and Technology, North University of China, Taiyuan 030051, China

全文: PDF(4554 KB) HTML

摘要:

结合杂环化合物和季铵盐表面活性剂用作缓蚀剂和杀菌剂的结构特点，合成了含噻二唑杂环的季铵盐表面活性剂 (MTOTB)，并采用¹HNMR、ESI-MS和FT-IR对其结构进行表征。采用表面张力法研究其表面活性，采用电化学测试和表面分析的方法研究其在含硫酸盐还原菌 (SRB) 的模拟海水中对碳钢的缓蚀性能。结果表明，MTOTB在模拟海水中的临界胶束浓度为0.11 mmol/L。MTOTB浓度为0.2 mmol/L时，对在含SRB菌的模拟海水中浸泡21 d的碳钢的缓蚀率可达95.81%。SEM/EDS与XPS结果表明，MTOTB可以有效地吸附在碳钢表面，抑制碳钢的微生物腐蚀。

关键词 ：季铵盐表面活性剂, 噻二唑衍生物, 表面活性, 分子内协同效应, 电化学测试, 硫酸盐还原菌

Abstract：

An ammonium salt surfactant containing thiadiazole (MTOTB) was synthesized as a novel inhibitor, aiming to combine the characteristics in corrosion inhibition and bactericidal property of heterocyclic compound and ammonium salt surfactant. The structure, surface activity and corrosion inhibition performance for carbon steel in simulated seawater with SRB of the prepared product were characterized by means of ¹HNMR, ESI-MS, FT-IR, surface tension measurements, electrochemical measurements and SEM-EDS. The results showed that the critical micelle concentration was 0.11 mmol/L for MTOTB in the simulated seawater. The inhibition efficiency could reach 95.81% for carbon steel in the simulated seawater with SRB for 21 d through addition of 0.2 mmol/L MTOTB. The results of SEM-EDS and XPS showed that MTOTB could adsorb on the surface of carbon steel effectively, so that inhibit the microbial corrosion of carbon steel.

Key words： ammonium salt surfactant thiadiazole derivative surface activity intramolecular synergistic effect electrochemical measurements sulfate-reducing bacteria

收稿日期: 2021-04-16

ZTFLH:

TG171

基金资助:国家自然科学基金(51701188);山西省自然科学基;金(201801D221088)

通讯作者: 朱海林 E-mail: zhuhailin@nuc.edu.cn

Corresponding author: ZHU Hailin E-mail: zhuhailin@nuc.edu.cn

作者简介: 朱海林，女，1982年生，博士，副教授

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引用本文:

朱海林, 陆小猛, 李晓芬, 王俊霞, 刘建华, 冯丽, 马雪梅, 胡志勇. 含噻二唑季铵盐表面活性剂的合成及缓蚀杀菌性能研究[J]. 中国腐蚀与防护学报, 2022, 42(1): 51-59.
Hailin ZHU, Xiaomeng LU, Xiaofen LI, Junxia WANG, Jianhua LIU, Li FENG, Xuemei MA, Zhiyong HU. Synthesis, Corrosion Inhibition and Bactericidal Performance of an Ammonium Salt Surfactant Containing Thiadiazole. Journal of Chinese Society for Corrosion and protection, 2022, 42(1): 51-59.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2021.082 或 https://www.jcscp.org/CN/Y2022/V42/I1/51

图1 含噻二唑季铵盐表面活性剂的合成路线

图2 MTOTB的ESI-MS谱图

图3 MTOTB的1HNMR谱图

图4 MTOTB的FT-IR光谱图

图5 MTOTB在30 ℃模拟海水中的γ-lgc曲线

图6 SRB在模拟海水中的生长曲线

图7 碳钢在添加不同浓度MTOTB的含SRB的30 ℃模拟海水中浸泡21 d后的Nyquist图和Bode图

图8 电化学阻抗谱等效电路图

表1 电化学阻抗谱拟合数据

图9 碳钢试样在浸泡前及在腐蚀介质中浸泡21 d后的表面SEM图，及其相应的EDS成分分析

图10 碳钢试样在不同介质中浸泡21 d的高分辨XPS能谱图

表2 碳钢试样在不同介质中浸泡21 d后的XPS谱图拟合参数

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