十二烷基苯磺酸钠在模拟混凝土孔隙液中对Q235钢缓蚀及吸附行为研究

doi:10.11902/1005.4537.2020.173

中国腐蚀与防护学报

2021, Vol. 41

Issue (6): 857-863 DOI: 10.11902/1005.4537.2020.173

研究报告

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十二烷基苯磺酸钠在模拟混凝土孔隙液中对Q235钢缓蚀及吸附行为研究

唐荣茂, 刘光明(

), 师超, 张帮彦, 田继红, 甘鸿禹, 刘永强

南昌航空大学材料科学与工程学院南昌 330063

Inhibition and Adsorption Behavior of Sodium Dodecyl-benzene Sulfonate on Q235 Steel in Simulated Concrete Pore Fluid

TANG Rongmao, LIU Guangming(

), SHI Chao, ZHANG Bangyan, TIAN Jihong, GAN Hongyu, LIU Yongqiang

School of Material Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China

全文: PDF(3535 KB) HTML

摘要:

采用动电位极化曲线、Mott-Schottky曲线与表面形貌分析等方法研究了十二烷基苯磺酸钠 (SDBS) 在0.5 mol/L NaCl和饱和Ca(OH)₂溶液 (SCP) 中对Q235钢的缓蚀作用及吸附行为。结果表明，SDBS浓度在0~8.315×10^-4 mol/L区间，SDBS在模拟混凝土孔隙液中对Q235钢具有较好的缓蚀效果，其缓蚀率随SDBS浓度的增加而增大。室温下添加8.315×10^-4 mol/L的SDBS其缓蚀率可达85.72%，且温度从298 K升至328 K过程中，缓蚀率逐渐降低。SDBS在Q235钢表面的吸附符合Langmuir型吸附等温式，吸附过程为放热、熵增的自发过程。SDBS在Q235钢表面的吸附是以化学吸附为主的混合吸附。SDBS在Q235钢表面形成的吸附膜将Cl^-等侵蚀性离子隔离，抑制了Q235钢腐蚀。

关键词 ：十二烷基苯磺酸钠, 模拟混凝土孔隙液, 缓蚀, 吸附行为

Abstract：

The corrosion inhibition and adsorption behavior of sodium dodecyl benzene sulfonate (SDBS) in the range of 0~8.315×10^-4 mol/L on Q235 steel in a simulated concrete pore fluid of 0.5 mol/L NaCl saturated Ca(OH)₂ solution were studied by means of potential polarization curve measurement, Mott-Schottky curve measurement and surface morphology analysis. SDBS has a good corrosion inhibition effect on Q235 steel in the simulated concrete pore fluid, and its corrosion inhibition rate increases with the increase of SDBS concentration. The addition of 8.315×10^-4 mol/L SDBS has a corrosion inhibition rate of 85.72% at room temperature, and the corrosion inhibition rate gradually decreases when the temperature rises from 298 K to 328 K.The adsorption of SDBS on the surface of Q235 steel conforms to the Langmuir adsorption isotherm. The adsorption process is a spontaneous process of exothermic and entropy increase. The adsorption of SDBS on the surface of Q235 steel is a mixed adsorption based on chemical adsorption. The adsorption film of SDBS formed on the surface of Q235 steel isolates the aggressive ions such as Cl^- and inhibits the corrosion of Q235 steel.

Key words： sodium dodecyl benzene sulfonate simulated concrete pore fluid corrosion inhibition adsorption behavior

收稿日期: 2020-09-24

ZTFLH:

TG147.2

基金资助:国家自然科学基金(51961028)

通讯作者: 刘光明 E-mail: gemliu@126.com

Corresponding author: LIU Guangming E-mail: gemliu@126.com

作者简介: 唐荣茂，男，1995年生，硕士生

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引用本文:

唐荣茂, 刘光明, 师超, 张帮彦, 田继红, 甘鸿禹, 刘永强. 十二烷基苯磺酸钠在模拟混凝土孔隙液中对Q235钢缓蚀及吸附行为研究[J]. 中国腐蚀与防护学报, 2021, 41(6): 857-863.
Rongmao TANG, Guangming LIU, Chao SHI, Bangyan ZHANG, Jihong TIAN, Hongyu GAN, Yongqiang LIU. Inhibition and Adsorption Behavior of Sodium Dodecyl-benzene Sulfonate on Q235 Steel in Simulated Concrete Pore Fluid. Journal of Chinese Society for Corrosion and protection, 2021, 41(6): 857-863.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.173 或 https://www.jcscp.org/CN/Y2021/V41/I6/857

图1 实验装置示意图

图2 Q235钢在含不同浓度SDBS的SCP溶液中的极化曲线

表1 Q235钢在含不同浓度SDBS的SCP溶液中的极化曲线拟合参数

图3 Q235钢在含不同浓度SDBS的SCP溶液中的Mott-Schottky曲线

表2 Q235钢在不同浓度SDBS的SCP溶液中的Mott-Schottky曲线拟合参数

图4 Q235钢在SCP溶液中腐蚀24 h的SEM形貌

图5 SDBS在Q235钢表面吸附的等温吸附模型拟合

表3 SDBS在Q235钢表面的等温吸附模型拟合参数

图6 SDBS浓度与温度对腐蚀电流密度和缓蚀率的影响

图7 SDBS在不同温度下的Langmuir型拟合曲线

表4 SDBS在不同温度下的Langmuir型拟合参数

图8 Q235钢在含不同浓度SDBS的SPC溶液中的Arrhen-ius拟合曲线

图9 lnK与1/T关系图

表5 SDBS在Q235钢表面吸附的热力学参数

1	Wang Y S, Zuo Y. The adsorption and inhibition behavior of two organic inhibitors for carbon steel in simulated concrete pore solution [J]. Corros. Sci., 2017, 118: 24
2	Feng L J, Zhao K W, Yang H Y, et al. Synergistic effect of inhibitors of an imidazoline derivative and tetraethylenepentamine on corrosion inhibition of steel rebar in an artifial concrete pore solution [J]. J. Chin. Soc. Corros. Prot., 2015, 35: 297
2	冯丽娟, 赵康文, 杨怀玉等. 混凝土模拟液中咪唑啉衍生物与四乙烯五胺间缓蚀协同效应 [J]. 中国腐蚀与防护学报, 2015, 35: 297
3	Zhu Y C, Liu G M, Liu X, et al. Investigation on interrelation of field corrosion test and accelerated corrosion test of grounding materials in red soil environment [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 550
3	朱亦晨, 刘光明, 刘欣等. 红壤地区接地材料现场埋样与加速腐蚀实验的相关性研究 [J]. 中国腐蚀与防护学报, 2019, 39: 550
4	Lin B. Study on inhibition effect of some organic inhibitors on carbon steel in carbonated simulatied concrete pore solutions [D]. Beijing: Beijing University of Chemical Technology, 2019
4	林冰. 模拟碳化混凝土孔隙液中几种有机缓蚀剂对碳钢的缓蚀作用 [D]. 北京: 北京化工大学, 2019
5	Liu M J, Wang J, Li C Y, et al. Study on adsorption thermodynamics and corrosion inhibition of sodium dodecylbenzene sulfonate on zinc in nitric acid [J]. Appl. Chem. Ind., 2007, 36: 355
5	刘明婧, 王佳, 李春颖等. 硝酸溶液中十二烷基苯磺酸钠对锌的缓蚀作用及吸附热力学研究 [J]. 应用化工, 2007, 36: 355
6	Feng L J, Zhao K W, Tang N, et al. Inhibition and synergistic effect of Mixtures of oxygen-containing organic compounds with sodium dodecyl benzene sulfate on steel rebar corrosion in 3.5%NaCl saturated Ca(OH)₂ solution [J]. J. Chin. Soc. Corros. Prot., 2013, 33: 441
6	冯丽娟, 赵康文, 唐囡等. 含氧有机物与十二烷基苯磺酸钠复配物在3.5%NaCl饱和Ca(OH)₂溶液中对钢筋的缓蚀与协同效应 [J]. 中国腐蚀与防护学报, 2013, 33: 441
7	Wang L, Gu W, Fu W, et al. The corrosion inhibition effect of sodium dodecylbenzene sulfonate on AZ31B magnesium alloy [J]. Appl. Chem. Ind., 2020, 49: 97
7	王丽, 顾威, 付文等. 十二烷基苯磺酸钠对AZ31B镁合金的缓释效果研究 [J]. 应用化工, 2020, 49: 97
8	Meng X J, Ji D C, Ge H H. Effect of sodium dodecylbeuzene sulfate on corrosion inhibition and surface tension of carbon steel in 3.5% NaCl-sodium molybdate solution [J]. Chem. World, 2014, 55: 472
8	孟新静, 季冬晨, 葛红花. 十二烷基苯磺酸钠对碳钢/3.5%NaCl-钼酸盐体系表面张力及缓蚀性能的影响 [J]. 化学世界, 2014, 55: 472
9	Cui X L. Flat band potential of semiconductor electrodes [J]. Chem. Bull., 2017, 80: 1160
9	崔晓莉. 半导体电极的平带电位 [J]. 化学通报, 2017, 80: 1160
10	Cao F T, Wei J, Dong J H, et al. Corrosion inhibition behavior of 1-hydroxyethylidene-1,1-diphosphonic acid on 20SiMn steel in simulated concrete pore solution containing Cl^- [J]. Acta Metall. Sin., 2020, 56: 898
10	曹凤婷, 魏洁, 董俊华等. 羟基亚乙基二膦酸对20SiMn钢在含Cl^-混凝土模拟孔隙液中的缓蚀行为 [J]. 金属学报, 2020, 56: 898
11	Wang Y S, Zuo Y, Zhao X H, et al. The adsorption and inhibition effect of calcium lignosulfonate on Q235 carbon steel in simulated concrete pore solution [J]. Appl. Surf. Sci., 2016, 379: 98
12	Xie W C, Li J S. Inhibition action and adsorption behavior of sodium lignosulphonate on Q235 steel in simulated concrete solution [J]. Mater. Rep., 2019, 33(8): 1401
12	谢婉晨, 李建三. 木质素磺酸钠在混凝土模拟孔隙液中对碳钢的缓蚀与吸附作用 [J]. 材料导报, 2019, 33(8): 1401
13	Li Y Z, Li B L, Yang T, et al. Studies on adsorption thermodynamics of sodium dodecyl benzene sulfonate on brass in mud acid [J]. Clean. World, 2008, 24(1): 1
13	李玉忠, 李佰玲, 杨婷等. 土酸中十二烷基苯磺酸钠对黄铜吸附热力学研究 [J]. 清洗世界, 2008, 24(1): 1
14	Zhao J M, Chen G H. The synergistic inhibition effect of oleic-based imidazoline and sodium benzoate on mild steel corrosion in a CO₂-saturated brine solution [J]. Electrochim. Acta, 2012, 69: 247
15	Alaneme KK, Olusegun S J. Corrosion inhibition performance of lignin extract of sun flower (Tithonia Diversifolia) on medium carbon low alloy steel immersed in H₂SO₄ solution [J]. Leonardo J. Sci., 2012, 20: 59
16	Yao Z M. Study on inhibition mechanism of environmental-friendly inhibitors for magnesium alloys [D]. Chongqing: Chongqing University, 2008
16	姚志明. 镁合金绿色缓蚀剂及其缓蚀机理研究 [D]. 重庆: 重庆大学, 2008
17	Zha Q X. Introduction to Electrode Process Dynamics [M]. Beijing: Science Press, 1976: 256
17	查全性. 电极过程动力学导论 [M]. 北京: 科学出版社, 1976: 256
18	Zhao Y Z, Pan T, Yu X T, et al. Corrosion inhibition efficiency of triethanolammonium dodecylbenzene sulfonate on Q235 carbon steel in simulated concrete pore solution [J]. Corros. Sci., 2019, 158: 108097
19	Wang Y S. Adsorption and corrosion inhibition of several organic inhibitors on carbon steel in simulated concrete pore solution [D]. Beijing: Beijing University of Chemical Technology, 2016
19	王怡珊. 模拟混凝土孔隙液中几种有机缓蚀剂在碳钢表面吸附及缓蚀行为研究 [D]. 北京: 北京化工大学, 2016
20	Li L J, Yao Z M, Lei J L, et al. Adsorption and corrosion inhibition behavior of sodium dodecyl benzene sulfonate on AZ31 magnesium alloy [J]. Acta Phys.-Chim. Sin., 2009, 25: 1332
20	李凌杰, 姚志明, 雷惊雷等. 十二烷基苯磺酸钠在AZ31镁合金表面的吸附及其缓蚀作用 [J]. 物理化学学报, 2009, 25: 1332
21	Liu Y S. Study on corrosion inhibitor of carbon steel in 3% sodium chlorrde solution [D]. Chongqing: Chongqing University, 2008
21	刘阳升. 3%NaCl介质中碳钢的缓蚀剂研究 [D]. 重庆: 重庆大学, 2008

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