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THE EFFECT OF RARE EARTH ADDITION TO Ni-P ALLOY PLATING BATH ON CORROSION RESISTANCE OF DEPOSITED LAYER |
Shao Guangjie;Wang Yulin;Shen Dejiu;Yu Jinku |
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Abstract The effect of rare earth addition to brush plating bath on structure and corrosion resistance of electrodenosited Ni-P alloy layer was studied.The results showed that the addition of 1g/L of blent rare earth could promote non-crystallization of the resulting Ni-P(RE)alloy layer,which was amorphous with even as low as only 5% P.The Ni-P (RE) alloy had higher corrosion resistance than Ni-P alloy without rare earth in 3.6% HCl solution and sea water.A mechanism of improvement was proposed.The rare earth ions might be adsorbed on the eledrode surface and interfered with normal discharge and diffusion of Ni2+ so as to promote the non-crystallization.
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Received: 25 February 1996
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1覃奇贤,奕本利,杨秀敏·电镀与精饰,1993,15(3):72王继荫,单国友·中国腐蚀与防护学报,1988,8(3):2403张若烨编著,申泮文审校·稀土元素化学,天津科学技术出版社,1987,p190 |
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