TEM Investigation to Oxide Scale Formed on Single Crystal Alloy FeCr15Ni15 at High Temperature

doi:10.11902/1005.4537.2019.155

Journal of Chinese Society for Corrosion and protection

2019, Vol. 39

Issue (5): 417-422 DOI: 10.11902/1005.4537.2019.155

Current Issue | Archive | Adv Search

TEM Investigation to Oxide Scale Formed on Single Crystal Alloy FeCr₁₅Ni₁₅ at High Temperature

WEI Xinxin^1,²,ZHANG Bo¹(

),MA Xiuliang¹

1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2. School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China

Download:

HTML

PDF(6827KB)
Export: BibTeX | EndNote (RIS)

Abstract

The oxide scale formed on FeCr₁₅Ni₁₅ single crystal alloy at 600 ℃ for 20 h was characterized by means of transmission electron microscope. Results showed that the oxide scale of 4~6 μm in thickness was differentiated into two layers. The inner layer of the scale was spinel oxide rich in Fe and Cr, while the outer layer was spinel oxide rich in Fe and Ni. The region I of inner layer was anisotropy, of which oxides present epitaxial growth along a large amount of (111) plane of the matrix, i.e. [110]_matrix//[110]_ox, (111)_matrix//(111)_ox, however the region II and region III compose completely of oxides, while there exist a large number of surface defects and holes left by the kirkendall effect, which become the most porous area of the oxide scale, therefore, as a result, cracking and spalling off may certainly occur there. In the contrast, the outer layer of the oxide scale is dense one composed of polycrystalline spinel oxides.

Key words: oxide scale TEM FeCr₁₅Ni₁₅ single crystal microstructure

Received: 12 September 2019

ZTFLH:

TG172

Fund: National Natural Science Foundation of China(51771212);Innovation Fund in IMR(2017-ZD05)

Corresponding Authors: Bo ZHANG E-mail: bozhang@imr.ac.cn

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Xinxin WEI
	Bo ZHANG
	Xiuliang MA

Cite this article:

WEI Xinxin,ZHANG Bo,MA Xiuliang. TEM Investigation to Oxide Scale Formed on Single Crystal Alloy FeCr₁₅Ni₁₅ at High Temperature. Journal of Chinese Society for Corrosion and protection, 2019, 39(5): 417-422.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2019.155 OR https://www.jcscp.org/EN/Y2019/V39/I5/417

Fig.1 Cross-sectional HAADF-STEM image of the oxide scale formed on the (110) surface of FeCr₁₅Ni₁₅ single crystal

Fig.2 EDS elemental mappings of the oxide scale formed on FeCr₁₅Ni₁₅ single crystal

Fig.3 Cross-sectional HAADF-STEM image of the inner area I of the oxide scale in Fig.1 (a) and the magnified images of areas 1 (b) and 2 (c) in Fig.3a

Fig.4 EDS elemental mappings of the inner area I of the oxide scale in Fig.1

Fig.5 High resolution HAADF-STEM image along [110] axis of the inner area I of the oxide scale in Fig.1 and the oxidation proceeds along a series of {111} close packed planes (a), the FFT diffractogram image of the selected area (b) and twin defects in the oxide scale (c)

Fig.6 Cross-sectional HAADF-STEM images of the inner areas II and III of the oxide scale in Fig.1: (a) HAADF-STEM image of the inner area II, (b) zoom-in image showing the high resolution HAADF-STEM image of Fig.6a, (c) HAADF-STEM image of the inner area III, (d) zoom-in image showing the high resolution HAADF-STEM image of Fig.6c

Fig.7 Cross-sectional TEM (a) and HAADF-STEM (b) images of the outer oxide layer in Fig.1

1	DingQ Q, YuQ, LiJ X, et al. Research progresses of rhenium effect in nickel based superalloys [J]. Mater. Rev., 2018, 32: 110
1	丁青青, 余倩, 李吉学等. 铼在镍基高温合金中作用机理的研究现状 [J]. 材料导报, 2018, 32: 110
2	WrightI G, DooleyR B. A review of the oxidation behaviour of structural alloys in steam [J]. Int. Mater. Rev., 2010, 55: 129
3	GaoX, WuX Q, GuanH, et al. Progress in study on corrosion scale formed in high-temperature and high-pressure water [J]. Corros. Sci. Prot. Technol., 2007, 19: 110
3	高欣, 吴欣强, 关辉等. 高温高压水环境中腐蚀产物膜的研究现状 [J]. 腐蚀科学与防护技术, 2007, 19: 110
4	MaC, PengQ J, HanE-H, et al. Review of stress corrosion cracking of structural materials in nuclear powerplants [J]. J. Chin. Soc. Corros. Prot., 2014, 34: 37
4	马成, 彭群家, 韩恩厚等. 核电结构材料应力腐蚀开裂的研究现状与进展 [J]. 中国腐蚀与防护学报, 2014, 34: 37
5	SunM C, WuX Q, ZhangZ E, et al. Oxidation of 316 stainless steel in supercritical water [J]. Corros. Sci., 2009, 51: 1069
6	ZiemniakS E, HansonM, SanderP C. Electropolishing effects on corrosion behavior of 304 stainless steel in high temperature, hydrogenated water [J]. Corros. Sci., 2008, 50: 2465
7	XieY, WuY Q, BurnsJ, et al. Characterization of stress corrosion cracks in Ni-based weld alloys 52, 52M and 152 grown in high-temperature water [J]. Mater. Charact., 2016, 112: 87
8	KuangW J, HanE-H, WuX Q, et al. Microstructural characteristics of the oxide scale formed on 304 stainless steel in oxygenated high temperature water [J]. Corros. Sci., 2010, 52: 3654
9	WagnerC. The electrochemistry of ionic crystals [J]. J. Electrochem. Soc., 1952, 99: C346
10	WagnerC. Reaktionstypen bei der oxydation von legierungen [J]. Zeitschrift Für Elektrochemie, 1959, 63: 772
11	AtkinsonA. Transport processes during the growth of oxide films at elevated temperature [J]. Rev. Mod. Phys., 1985, 57: 437
12	CabreraN, MottN F. Theory of the oxidation of metals [J]. Rep. Prog. Phys., 1949, 12: 163
13	EvansH E. Stress effects in high temperature oxidation of metals [J]. Int. Mater. Rev., 1995, 40: 1
14	DaviesD E, EvansU R, AgarJ N. The oxidation of iron at 175 to 350 ℃ [J]. Proc. Roy. Soc. London, 1954, 225A: 443
15	LiZ Y, CaiZ B, ZhouT, et al. Characteristics and formation mechanism of oxide film on 304 stainless steel in high temperature water [J]. Mater. Chem. Phys., 2019, 222: 267
16	CaoX Y, ZhuP, WangW, et al. Effect of thermal aging on oxide film of stainless steel weld overlay cladding exposed to high temperature water [J]. Mater. Charact., 2018, 138: 195
17	MaH, ChenX Q, LiR H, et al. First-principles modeling of anisotropic anodic dissolution of metals and alloys in corrosive environments [J]. Acta Mater., 2017, 130: 137
18	SongG L, XuZ Q. Effect of microstructure evolution on corrosion of different crystal surfaces of AZ31 Mg alloy in a chloride containing solution [J]. Corros. Sci., 2012, 54: 97
19	SongG L, MishraR, XuZ Q. Crystallographic orientation and electrochemical activity of AZ31 Mg alloy [J]. Electrochem. Commun., 2010, 12: 1009
20	GrayJ J, El DasherB S, OrmeC A. Competitive effects of metal dissolution and passivation modulated by surface structure: An AFM and EBSD study of the corrosion of alloy 22 [J]. Surf. Sci., 2006, 600: 2488
21	YassarR S, ScudieroL, AlamrA S, et al. Microstructure-mechanical and chemical behavior relationships in passive thin films [J]. Thin Solid Films, 2010, 518: 2757
22	ZhangB, SanX Y, WeiX X, et al. Quasi-in-situ observing the growth of native oxide film on the FeCr15Ni15 austenitic alloy by TEM [J]. Corros. Sci., 2018, 140: 1
23	WangW, CaoX Y, LuY H, et al. TEM study on oxide mechanism of the dissimilar welds between 316 stainless steels/Inconel 182 in high temperature and high pressure water [J]. Mater. Charact., 2017, 131: 339
24	ZhengS J, WangY J, ZhangB, et al. Identification of MnCr2O4 nano-octahedron in catalysing pitting corrosion of austenitic stainless steels [J]. Acta Mater., 2010, 58: 5070
25	ChenC L, LiH P, SekiT, et al. Direct determination of atomic structure and magnetic coupling of magnetite twin boundaries [J]. ACS Nano, 2018, 12: 2662
26	PrattA, LariL, HovorkaO, et al. Enhanced oxidation of nanoparticles through strain-mediated ionic transport [J]. Nat. Mater., 2014, 13: 26
27	YinY D, RiouxR M, ErdonmezC K, et al. Formation of hollow nanocrystals through the nanoscale kirkendall effect [J]. Science, 2004, 304: 711

[1]	REN Yan, QIAN Yuhai, ZHANG Xintao, XU Jingjun, ZUO Jun, LI Meishuan. Effect of Thermal Shock on Mechanical Properties of Siliconized Graphite with ZrB₂-SiC-La₂O₃/SiC Coating[J]. 中国腐蚀与防护学报, 2021, 41(1): 29-35.
[2]	WANG Lei, DONG Junhua, HAN Da, LIANG Jiankun, LI Quan, KE Wei. Phenonmenon of Cu Segregation in Cu-containing steel During Soaking at 1150 ℃[J]. 中国腐蚀与防护学报, 2020, 40(6): 545-552.
[3]	LIU Xiao, WANG Hai, ZHU Zhongliang, LI Ruitao, CHEN Zhenyu, FANG Xudong, XU Fanghong, ZHANG Naiqiang. Oxidation Characteristics of Austenitic Heat-resistant Steel HR3C and Sanicro25 in Supercritical Water for Power Station[J]. 中国腐蚀与防护学报, 2020, 40(6): 529-538.
[4]	YU Haoran, ZHANG Wenli, CUI Zhongyu. Difference in Corrosion Behavior of Four Mg-alloys in Cl^--NH₄⁺-NO₃^- Containing Solution[J]. 中国腐蚀与防护学报, 2020, 40(6): 553-559.
[5]	ZHAI Sixin, YANG Xingyun, YANG Jilan, GU Jianfeng. Corrosion Properties of Quenching-Partitioning-Tempering Steel in Simulated Seawater[J]. 中国腐蚀与防护学报, 2020, 40(5): 398-408.
[6]	LI Congwei, DU Shuangming, ZENG Zhilin, LIU Eryong, WANG Feihu, MA Fuliang. Effect of Current Density on Microstructure, Wear and Corrosion Resistance of Electrodeposited Ni-Co-B Coating[J]. 中国腐蚀与防护学报, 2020, 40(5): 439-447.
[7]	WEN Yang, XIONG Lin, CHEN Wei, XUE Gang, SONG Wenxue. Chloride Penetration Resistance of Polyvinyl Alcohol Fiber Concrete under Dry and Wet Cycle in Chloride Salt Solutions[J]. 中国腐蚀与防护学报, 2020, 40(4): 381-388.
[8]	XIE Dongbai, HONG Hao, WANG Wen, PENG Xiao, DUO Shuwang. Oxidation Behavior of Stainless Steel 1Cr11Ni2W2MoV in a Simulated Kerosene Combustion Environment[J]. 中国腐蚀与防护学报, 2020, 40(4): 358-366.
[9]	WANG Haiwei, CHANG Sen, LUAN Xin'gang, SONG Xuemei, WANG Zhen, LI Yanzhang, CHEN Jianli, ZHANG Jirong, HAN Ming, QIU Dangui. Preparation and Properties of Ceramics Composed of Nano-Al₂O₃ and Polysiloxane-polyborosilicate-TiB₂ Modified Polysilborazane as High Temperature Adhesive for SiC Based Ceramics[J]. 中国腐蚀与防护学报, 2020, 40(4): 367-372.
[10]	ZHANG Zhen, WU Xinqiang, TAN Jibo. *Review of Electrochemical Noise Technique for in situ* Monitoring of Stress Corrosion Cracking**[J]. 中国腐蚀与防护学报, 2020, 40(3): 223-229.
[11]	SHEN Shuyang, WANG Dongsheng, SUN Shibin, YANG Ti, ZHAO Qianjing, WANG Xin, ZHANG Yafei, CHANG Xueting. Corrosion Behavior in Artificial Seawater of Subzero Treated EH40 Marine Steel Suitable for ExtremelyCold Environments[J]. 中国腐蚀与防护学报, 2020, 40(2): 151-158.
[12]	ZHENG Yanxin, LIU Ying, SONG Qingsong, ZHENG Feng, JIA Yuchuan, HAN Peide. High-temperature Oxidation Behavior and Wear Resistance of Copper-based Composites with Reinforcers of C, ZrSiO₄ and Fe[J]. 中国腐蚀与防护学报, 2020, 40(2): 191-198.
[13]	FAN Yi,CHEN Linheng,CAI Jiaxing,DAi Qinqin,MA Hongchi,CHENG Xuequn. Corrosion Behavior of Hot-rolled AH36 Plate in Indoor Storage Environment[J]. 中国腐蚀与防护学报, 2020, 40(1): 10-16.
[14]	WU Dongcai,HAN Peide. Effects of Moderate Temperature Aging Treatment on Corrosion Resistance of SAF2304 DuplexStainless Steel[J]. 中国腐蚀与防护学报, 2020, 40(1): 51-56.
[15]	XU Xunhu,HE Cuiqun,XIANG Junhuai,WANG Ling,ZHANG Honghua,ZHENG Xiaodong. High Temperature Oxidation Behavior of Co-20Re-25Cr-1Si Alloy in 0.1 MPa Pure Oxygen[J]. 中国腐蚀与防护学报, 2020, 40(1): 75-80.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed