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Journal of Chinese Society for Corrosion and protection  2019, Vol. 39 Issue (3): 274-280    DOI: 10.11902/1005.4537.2018.129
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Corrosion Behavior of Low-alloy High Strength Steels in a Simulated Common SO2-containing Atmosphere
Yongwei SUN(),Yuping ZHONG,Lingshui WANG,Fangxiong FAN,Yatao CHEN
Luoyang Sunrui Special Equipment Co. Ltd., Luoyang Ship Material Research Institute, Luoyang 471000, China
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Abstract  

The corrosion resistance of Q345E and Cr-Ni-Cu steels was comparatively assessed by means of potentiodynamic polarization and cyclic immersion corrosion tests in 0.052% (mass fraction) NaHSO3 solution, which aims to simulate the common SO2-containing atmosphere. The characteristic of corrosion rust was studied by means of scanning electron microscope (SEM) and X-ray diffraction (XRD). Results show that the open circuit corrosion potential of Q345E and Cr-Ni-Cu steel are -730 and -705 mV, respectively. The rust layers of two steels contain γ-FeO(OH) and α-Fe phase. Some α-FeO(OH) and Fe3O4 products generate with increasing of the corrosion time. Compared with Q345E steel, the Cr-Ni-Cu steel has lower corrosion rate due to the formation of a much more compact rust layer containing elements such as Cr, Ni and Cu, which are beneficial to corrosion resistance.

Key words:  low-alloy high strength steel      atmospheric corrosion      rust characteristic      cyclic immersion corrosion      corrosion rate     
Received:  07 September 2018     
ZTFLH:  TG142.4  
Fund: Key Projects of Science and Technology of Henan Province(182102210437)
Corresponding Authors:  Yongwei SUN     E-mail:  weiyong09@163.com

Cite this article: 

Yongwei SUN,Yuping ZHONG,Lingshui WANG,Fangxiong FAN,Yatao CHEN. Corrosion Behavior of Low-alloy High Strength Steels in a Simulated Common SO2-containing Atmosphere. Journal of Chinese Society for Corrosion and protection, 2019, 39(3): 274-280.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2018.129     OR     https://www.jcscp.org/EN/Y2019/V39/I3/274

SteelCSiMnPSCrNiCuAlFe
Q345E0.180.251.600.020.0020.030.010.01---Bal.
A0.120.350.800.040.0050.200.250.100.01Bal.
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[1] Wang J R, Zhang Z, Zhu L Q, et al. Research on mathematical model of carbon steel and low alloy steel in atmosphere [J]. J. Aeronaut. Mater., 2004, 24(1): 41
[1] (王景茹, 张峥, 朱立群等. 碳钢、低合金钢大气腐蚀数学模型研究 [J]. 航空材料学报, 2004, 24(1): 41)
[2] Zhou W H, Xie Z J, Guo H, et al. Regulation of multi-phase microstructure and mechanical properties in a 700 MPa grade low carbon low alloy steel with good ductility [J]. Acta Metall. Sin., 2015, 51: 407
[2] (周文浩, 谢振家, 郭晖等. 700 MPa级高塑低碳低合金钢的多相组织调控及性能 [J]. 金属学报, 2015, 51: 407)
[3] Li J, Zhang X Z, Liu J S. Static recrystallization models of low-alloy Q345E steel [J]. Heavy Cast. Forg., 2014, (1): 14
[3] (李佳, 张秀芝, 刘建生. 低合金钢Q345E静态再结晶模型研究 [J]. 大型铸锻件, 2014, (1): 14)
[4] Cai H C. Electrochemical testing method of low alloy steel in atmospheric corrosion [J]. Res. Iron Steel, 1986, 39(2): 29
[4] (蔡慧超. 低合金钢大气腐蚀电化学测试方法 [J]. 钢铁研究, 1986, 39(2): 29)
[5] Han W, Wang J, Wang Z Y, et al. Study on atmospheric corrosion of low alloy steels [J]. J. Chin. Soc. Corros. Prot., 2004, 24: 147
[5] (韩薇, 汪俊, 王振尧等. 碳钢与低合金钢耐大气腐蚀规律研究 [J]. 中国腐蚀与防护学报, 2004, 24: 147)
[6] Tewary N K, Kundu A, Nandi R, et al. Microstructural characterisation and corrosion performance of old railway girder bridge steel and modern weathering structural steel [J]. Corros. Sci., 2016, 113: 57
[7] Guo M X, Pan C, Wang Z Y, et al. A study on the initial corrosion behavior of carbon steel exposed to a simulated coastal-industrial atmosphere [J]. Acta Metall. Sin., 2018, 54: 65
[7] (郭明晓, 潘晨, 王振尧等. 碳钢在模拟海洋工业大气环境中初期腐蚀行为研究 [J]. 金属学报, 2018, 54: 65)
[8] Urban V, Krivy V, Kubzova M. Development of corrosion processes on weathering railway bridge [J]. Proced. Eng., 2017, 190: 275
[9] Morcillo M, Chico B, Díaz I, et al. Atmospheric corrosion data of weathering steels. A review [J]. Corros. Sci., 2013, 77: 6
[10] Mi F Y. The effect of rare earth on industrial and sea atmosphere corrosion resistance for low alloy steel [D]. Kunming: Kunming University of Science and Technology, 2011
[10] (米丰毅. 稀土对低碳结构钢耐工业及海洋大气腐蚀性能的影响研究 [D]. 昆明: 昆明理工大学, 2011)
[11] Ma X Y, Wang X Y, Qu Z Y, et al. Comparison of several different models in atmospheric corrosion prediction [J]. J. Univ. Sci. Technol. Beijing, 2000, 22: 145
[11] (马小彦, 汪轩义, 屈祖玉等. 几种不同大气腐蚀预测模型的比较 [J]. 北京科技大学学报, 2000, 22: 145)
[12] Yu Q, Dong C F, Fang Y H, et al. Atmospheric corrosion of Q235 carbon steel and Q450 weathering steel in Turpan, China [J]. J. Iron Steel Res. Int., 2016, 23: 1061
[13] Wu Z F, Song Y Q, Feng Y F, et al. Study on corrosion behavior of low alloy high strength weathering steel in simulated industrial atmosphere under wet and dry alternating condition [J]. Hot Work. Technol., 2017, 46(12): 104
[13] (吴志锋, 宋义全, 冯宇飞等. 低合金高强度耐候钢在干湿交替环境下模拟工业大气的腐蚀行为研究 [J]. 热加工工艺, 2017, 46(12): 104)
[14] Cao G L, Li G M, Chen S, et al. Comparison on pitting corrosion resistance of nickel and chromium in typical sea water resistance steels [J]. Acta Metall. Sin., 2010, 46: 748
[14] (曹国良, 李国明, 陈珊等. 典型耐海水腐蚀钢中Ni和Cr耐点蚀作用的比较 [J]. 金属学报, 2010, 46: 748)
[15] Choi Y S, Shim J J, Kim J G. Corrosion behavior of low alloy steels containing Cr, Co and W in synthetic potable water [J]. Mater. Sci. Eng., 2004, A385: 148
[16] Ke W, Dong J H. Study on the rusting evolution and the performance of resisting to atmospheric corrosion for Mn-Cu steel [J]. Acta Metall. Sin., 2010, 46: 1365
[16] (柯伟, 董俊华. Mn-Cu钢大气腐蚀锈层演化规律及其耐候性的研究 [J]. 金属学报, 2010, 46: 1365)
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