Preparation and Properties of Organosilicone/SiO2Hybrid Sol Modified Acrylic Resin

doi:10.11902/1005.4537.2017.208

Journal of Chinese Society for Corrosion and protection

2018, Vol. 38

Issue (6): 601-606 DOI: 10.11902/1005.4537.2017.208

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Preparation and Properties of Organosilicone/SiO₂Hybrid Sol Modified Acrylic Resin

Xiuling LAN¹,Guangming LIU¹(

),Jiesheng ZHOU²,Zhilei LIU¹,Shusen PENG¹,Maodong LI²

1. School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China
2. Guangzhou Special Pressure Equipment Testing Institute, Guangzhou 510000, China

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Abstract

Organosilicon/SiO₂hybrid sols modified water borne acrylic resins were synthesized via solution polymerization process with acrylic-acid (AA), butyl-acrylate (BA), hydroxyethyl-acrylate (HEA), methyl-methacrylate (MMA), tetraethyl (TEOS), 3-methacryloxypropyltrimethoxysilane (KH-570), methyltriethoxysilane (MTES) and diphenyl dimethoxy silane as raw material. The effect of different amount and specie of organosilicon/SiO₂hybrid sols on the properties of the resin was investigated. The structure of the prepared sols and resin films were characterized by infrared spectroscopy (FT-IR). The corrosion resistance and mechanical properties of the coatings on tinplate were as examined by means of immersion test, electrochemical impedance spectroscopy (EIS) and relevant mechanical testing means. The results showed that the organosilicon/SiO₂hybrid sol could be successfully grafted onto the acrylic molecules. Among others, the hybrid resin coating with 10% (mass fraction) organosilicon/SiO₂hybrid sol exhibited excellent comprehensive performance: such as excellent flexibility and adhesion; hardness and gloss as high as 6H and 104, respectively, while high corrosion resistance and long term stabilityetc.

Key words: acrylic-acid hybrid sol electrochemical impedance spectroscopy corrosion-resistance

Received: 08 December 2017

ZTFLH:

TQ632.4

Fund: Supported by National Natural Science Foundation of China(51501214);Guangdong Provincial Quality and Technical Supervision Bureau Science and Technology Project(2017CT14);Ningbo Natural Science Fund Project(2015A610060)

Corresponding Authors: Guangming LIU E-mail: gemliu@126.com

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	Xiuling LAN
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	Maodong LI

Cite this article:

Xiuling LAN,Guangming LIU,Jiesheng ZHOU,Zhilei LIU,Shusen PENG,Maodong LI. Preparation and Properties of Organosilicone/SiO₂Hybrid Sol Modified Acrylic Resin. Journal of Chinese Society for Corrosion and protection, 2018, 38(6): 601-606.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2017.208 OR https://www.jcscp.org/EN/Y2018/V38/I6/601

Table 1 Physical properties of silicone/SiO₂modified ac-rylic resin coatings

Table 2 Effects of the content of organosilicon/SiO₂hybrid sol on the physical properties of the coatings

Fig.1 FT-IR of four organosilicon/SiO₂hybrid sols

Fig.2 FT-IR results of water-borne acrylic resin modifided by organosilicon/SiO₂hybrid sol

Fig.3 Nyquist (a) and Bode (b) plots of the modified acryl- ic resin coatings immersed in 3.5%NaCl solution for 30 h

Fig.4 Nyquist (a) and Bode (b) plots of the modified acryl-ic resin coatings immersed in 3.5%NaCl solution for 300 h

Fig.5 Equivalent circuit of EIS of the modified acrylic resin coatings immersed in 3.5%NaCl solution for 30 and 300 h

Table 3 Fitting values of various parameters of EIS for the modified acrylic resin coatings immersed in 3.5%NaCl solution for 30 and 300 h

[1]	Duan Y F,Huo Y D,Duan L.Preparation of acrylic resins modified with epoxy resins and their behaviors as binders of waterborne printing ink on plastic film[J].Colloids Surf. A: Physicochem. Eng. Asp.,2017,535:225
[2]	Goodarzi I M,Farzam M,Shishesaz M R,et al.Eco-friendly, acrylic resin-modified potassium silicate as water-based vehicle for anticorrosive zinc-rich primers[J]. J Appl. Polym. Sci.,2014,131:40370
[3]	Pilch-Pitera B,Kozakiewicz J,Ofat I,et al.Silicone-acrylic hybrid aqueous dispersions of core-shell particle structure and corresponding silicone-acrylic nanopowders designed for modification of powder coatings and plastics. Part III: Effect of modification with selected silicone-acrylic nanopowders on properties of polyurethane powder coatings[J].Prog. Org. Coat.,2015,78:429
[4]	Yuan Y,Chen N,Liu R,et al.A novel acrylic prepolymer/methacrylate modified nano-SiO2composite used for negative photoresist[J].Mater. Res. Bull.,2014,50:392
[5]	Jang D E,Lee J Y,Jang H S,et al.Color stability, water sorption and cytotoxicity of thermoplastic acrylic resin for non metal clasp denture[J]. J. Adv. Prosthodont.,2015,7:278
[6]	Li K Z,Guo Q,Zhang L L,et al.Synthesis and characterization of Si-substituted hydroxyapatite bioactive coating for SiC-coated carbon/carbon composites[J].Ceram. Int.,2017,43:1410
[7]	Hamdy A S,Butt D P.Environmentally compliant silica conversion coatings prepared by sol-gel method for aluminum alloys[J].Surf. Coat. Technol.,2006,201:401
[8]	Easton T,Poultney S.Waterborne silicone-organic hybrid coatings for exterior applications[J]. J Coat. Technol. Res.,2007,4:187
[9]	Martínez-Zapata O,Méndez-Vivar J,Bosch P,et al.Synthesis and characterization of amorphous aluminosilicates prepared by sol-gel to encapsulate organic dyes[J]. J. Non-Cryst. Solids,2011,357:3480
[10]	Zhang J H,Chen Y S.Studies on application of sol-gel method[J].Guangdong Chem. Ind.,2008,35(3):47
[10]	张健泓,陈优生.溶胶-凝胶法的应用研究[J].广东化工,2008,35(3):47
[11]	Ma L,Wang G J,Dai J F.Preparation and properties of reduced graphene oxide/polyimide composites produced byin-situpolymerization and solution blending methods[J].New Carbon Mater.,2016,31:129
[11]	马朗,王国建,戴进峰.原位聚合法与溶液混合法制备石墨烯/聚酰亚胺复合材料及其性能[J].新型碳材料,2016,31:129
[12]	Chen G,Liu G M,Yao J,et al.Study on the electrochemical impedance spectroscopy of silicone/SiO2hybrid coating[J].Surf. Technol.,2008,37(6):47
[12]	陈刚,刘光明,姚敬等.有机硅/SiO2杂化涂层电化学阻抗研究[J].表面技术,2008,37(6):47
[13]	Liu G M,Yang X D,Lin J Y,et al.Influence of MTES content on the properties of Al2O3/organosilicone/SiO2hybrid coatings[J].Chin. J. Mater. Res.,2012,26:402
[13]	刘光明,杨晓东,林继月等.MTES含量对Al2O3/有机硅/SiO2杂化涂层性能的影响[J].材料研究学报,2012,26:402
[14]	Lin J Y,Liu G M,Chen G.Influence of DDS content on the properties of organosilicon/SiO2hybrid coatings[J]. J Chin. Soc. Corros. Prot., 2011,31:116
[14]	(林继月, 刘光明, 陈刚. DDS含量对有机硅/SiO2杂化涂层性能的影响[J].中国腐蚀与防护学报,2011,31:116
[15]	Kozakiewicz J,Ofat I,Trzaskowska J.Silicone-containing aqueous polymer dispersions with hybrid particle structure[J].Adv. Colloid Interface Sci.,2015,223:1

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