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| Corrosion Mechanism of Oil-fired Boiler in Power Plant and Progresses in Anticorrosion Techniques Inside Boiler |
Shuyuan LIANG, Cuiyu JIANG( ) |
| College of Science, China University of Petroleum, Qingdao 266580, China |
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Abstract The corrosion types encountered in oil-fired boiler plants were introduced, and the mechanisms related with high- and low-temperature corrosion were elucided. The relevant anticorrosion countermeasures were reviewed with emphasis on cold-end additives, chemical cleaning agents and boiler fuel additives etc., meanwhile, the anticorrosion mechanisms and application characteristics of these additives were also described respectively. The current status of anticorrosion studies for oil-fired boiler in power plant and the necessities of intensive studies on anticorrosion treatment were pointed out, the prospects of anticorrosion treatment were forecasted.
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Received: 05 March 2017
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| [1] | Tian S B.Distribution of different sulfur compounds in mideast crude oils[J]. Petrochem. Corros. Prot., 1997, 14: 1(田松柏. 中东原油中不同类型硫化合物的分布[J]. 石油化工腐蚀与防护, 1997, 14: 1) | | [2] | Speight J G.The Desulfurization of Heavy Oils and Residua [M]. Boca Raton: CRC Press, 1999 | | [3] | Hiroo N, Atsushi N, Shiro H.Electrochemistry of corrosion in molten salt[J]. Jpn. Soc. Corros. Eng., 1984, 33: 103(沼田博雄, 西方篤, 春山志郎. 溶融塩中における腐食の電気化学[J]. 防食技術, 1984, 33: 103) | | [4] | Rapp R A.Hot corrosion of materials: A fluxing mechanism?[J]. Corros. Sci., 2002, 44: 209 | | [5] | Bornstein N S, Decrescente M A.The role of sodium in the accelerated oxidation phenomenon termed sulfidation[J]. Metall. Trans., 1971, 2: 2875 | | [6] | Liu Y, Shi J C, Shang H, et al.Study on the performance of microwave radiation promoted removal of nickel and vanadium heavy metals from crude oil[J]. Vac. Electron., 2013, (6): 49(刘煜, 石金春, 商辉等. 微波辐射脱除石油中镍、钒重金属的性能研究[J]. 真空电子技术, 2013, (6): 49) | | [7] | Ren X, Yang H Y, Wang F H, et al.Progress on vanadium induced corrosion[J]. Corros. Sci. Prot. Technol., 2001, 13: 338(任鑫, 杨怀玉, 王福会等. 重金属钒腐蚀的研究进展[J]. 腐蚀科学与防护技术, 2001, 13: 338) | | [8] | Harada Y, Nakamori M.Low molten compounds in oil ash and prevention of high temperature corrosion with Mg(OH)2 additive[J]. Zairyo-to-Kankyo, 1980, 29: 615 | | [9] | Cunningham G W, Brasunas A D S. The effects of contamination by vanadium and sodium compounds on the air-corrosion of stainless steel[J]. Corrosion, 1956, 12: 35 | | [10] | Kerby R C, Wilson J R.Corrosion of metals by liquid vanadium pentoxide and the sodium vanadates[J]. J. Eng. Gas Turb. Power, 1973, 95: 36 | | [11] | Harada Y.High temperature corrosion of oil firing boilers[J]. Zairyo-to-Kankyo, 1977, 26: 471 | | [12] | Yuan Y.Preliminary exploration of low oxygen combustion in large fuel fired boiler[J]. Electr. Power, 1978, (1): 28(袁颖. 大型燃油锅炉低氧燃烧的初步探索[J]. 中国电力, 1978, (1): 28) | | [13] | Tian S B.Testing methods for active sulfur in crude oil and distillates[J]. Petrochem. Corros. Prot., 1999, 16: 25(田松柏. 原油及其馏分油中活性硫的测定方法[J]. 石油化工腐蚀与防护, 1999, 16: 25) | | [14] | Bian L Y.Researchon the low temperature corrosion of regenerative air heater in power plant boiler[J]. Boil. Technol., 2016, 47: 26(边乐永. 电站锅炉回转式空气预热器低温腐蚀研究[J]. 锅炉技术, 2016, 47: 26) | | [15] | Tallermo H, Klevtsov I, Dedov A.Corrosion of air preheater tubes of oil shale CFB boiler. Part II. Laboratory investigation of temperature impact[J]. Oil Shale, 2009, 26: 13 | | [16] | Cao Y, Feng W Z.Analysis and prevention of low temperature corrosion problems in the back-end equipments of coal-fired boiler[J]. East China Electr. Power, 2014, 42: 391(曹艳, 冯伟忠. 燃煤锅炉尾部设备低温腐蚀问题分析及防治[J]. 华东电力, 2014, 42: 391) | | [17] | Li Z M, Sun F Z, Shi Y T, et al.Experimental study and mechanism analysis on low temperature corrosion of coal fired boiler heating surface[J]. Appl. Therm. Eng., 2015, 80: 355 | | [18] | Liu B.Thermal corrosion caused by vanadium in a fuel oil boiler and its protection[J]. Metall. Power, 1996, (4): 24(刘斌. 燃油锅炉中钒诱导的热腐蚀及其防治[J]. 冶金动力, 1996, (4): 24) | | [19] | Meadowcroft D B.High temperature corrosion of alloys and coatings in oil- and coal-fired boilers[J]. Mater. Sci. Eng., 1987, 88: 313 | | [20] | Wang S Q, Huang X Z.Research on high temperature corrosion property of boiler heating surface with high Ni-Cr alloy coating[J]. J. Shenyang Inst. Eng.(Nat. Sci.), 2008, 4: 23(王树群, 黄新章. 高Ni-Cr合金涂层防护锅炉受热面高温腐蚀的性能研究[J]. 沈阳工程学院学报(自然科学版), 2008, 4: 23) | | [21] | Kumar M, Singh H, Singh N, et al.Development of erosion-corrosion-resistant cold-spray nanostructured Ni-20Cr coating for coal-fired boiler applications[J]. J. Therm. Spray Technol., 2015, 24: 1441 | | [22] | Ren X, Yang X J, Lu L D, et al.Corrosion of aluminized steel in high temperature oil ash[J]. Mater. Prot., 2003, 36: 19(任鑫, 杨绪杰, 陆路德等. 渗铝钢在高温灰分中的腐蚀[J]. 材料保护, 2003, 36: 19) | | [23] | Qian Y H, Li Z G, Yang A N.Application and properties of low alloying sulfuric acid dew point corrosion- resistant steels[J]. Spec. Steel, 2005, 26: 30(钱余海, 李自刚, 杨阿娜. 低合金耐硫酸露点腐蚀钢的性能和应用[J]. 特殊钢, 2005, 26: 30) | | [24] | Hu H Z.A kind of anticorrosion steel suitable for box making[J]. Containerization, 1996, (6): 7(胡海舟. 一种适于造箱的耐腐蚀钢材——CORTEN钢漫话[J]. 集装箱化, 1996, (6): 7) | | [25] | Zhang Z X, Zhang Z C, Ye Q J, et al.Study of dewpoint corrosion of coal-fired boiler[J]. J. Mater. Eng., 2012, (8): 19(张知翔, 张智超, 曳前进等. 燃煤锅炉露点腐蚀实验研究[J]. 材料工程, 2012, (8): 19) | | [26] | Liu G Y.Research on enamelling on corten steel[J]. Glass Enamel, 2006, 34: 34(刘广阳. 考登钢表面涂搪瓷的研究[J]. 玻璃与搪瓷, 2006, 34: 34) | | [27] | Gu X M, Cai C Z.Application of air preheaters with enamelled tubers[J]. Power Equip., 2003, 17: 54(顾雪梅, 蔡昌忠. 搪瓷管空气预热器的应用[J]. 发电设备, 2003, 17: 54) | | [28] | Shayan M R, Ranjbar K, Hajidavalloo E, et al.On the failure analysis of an air preheater in a steam power plant[J]. J. Fail. Anal. Prev., 2015, 15: 941 | | [29] | Chen W T.Application of al-diffused steel tube in low-temperature heating service of boiler[J]. Corros. Prot. Petrochem. Ind., 2006, 23: 50(陈文婷. 渗铝管在锅炉低温受热面中的应用[J]. 石油化工腐蚀与防护, 2006, 23: 50) | | [30] | Chen W T.Application of an anti low temperature corrosion material-aluminizing pipe [A]. Chinese Petroleum Chemical Engineering Survey and Design Association, the National Committee of the Thermal Chemical Thermal Design Technology Center 2011 Annual Meeting[C]. Guilin: 2011(陈文婷. 抗低温腐蚀材料——渗铝管的应用 [A]. 中国石油和化工勘察设计协会热工专委会、热工中心站2011年年会[C]. 桂林: 2011) | | [31] | Le C Y.Application of cold end additives to boilers in the US and British power plants[J]. East China Electr. Power, 1985, (10): 65(乐长义. 冷端添加剂在美、英电站锅炉上的应用[J]. 华东电力, 1985, (10): 65) | | [32] | Le C Y.Various control techniques for cold end corrosion of pow-er plant boilers[J]. East China Electr. Power, 1986, (2): 1(乐长义. 电站锅炉冷端腐蚀的各种控制技术[J]. 华东电力, 1986, (2): 1) | | [33] | Shale C C, Simpson D G, Lewis P S.Removal of sulfur and nitrogen oxides from stack gases by ammonia[J]. Chem. Eng. Prog. Symp. Ser., 1971, 67: 52 | | [34] | Douglas J E, Kenyon G L, Kollman P A.The ammonia—sulfur trioxide interaction. An ab initio study[J]. Chem. Phys. Lett., 1978, 57: 553 | | [35] | Qi G J, Wang S J, Gao J B, et al.Simultaneous absorption of SO2 and CO2 from flue gas using aqueous ammonia[J]. J. Tsinghua Univ.(Sci. Technol.), 2016, 56: 885 | | [36] | Zheng X Y.Experimental study on SO2 and CO2 recovery from flue gases by ammonia [D]. Beijing: Tsinghua University, 2002(郑显玉. 氨法回收电厂烟气中二氧化硫二氧化碳的试验研究 [D]. 北京: 清华大学, 2002) | | [37] | Qi H L, Jiang D.Discussion on removal of SO2 from boiler flue gas by ammonia rich water[J]. Environ. Prot. Metall. Ind., 2000, (5): 58(亓海录, 江丹. 利用富氨水脱除锅炉烟气中SO2技术探讨[J]. 冶金环境保护, 2000, (5): 58) | | [38] | Niu J A.Pneumatic conveyer system for powdered additive feeding into cold end of a 1000 t/h oil-fired boiler[J]. East China Electr. Power, 1991, 19: 5(钮家鳌. 1000 t/h燃油锅炉冷端添加剂的输送系统[J]. 华东电力, 1991, 19: 5) | | [39] | Sada E, Kumazawa H, Nishimura H.Absorption of sulfur dioxide into aqueous double slurries containing limestone and magnesium hydroxide[J]. AIChE J., 1983, 29: 60 | | [40] | Ukai N, Murakami M, Okino S, et al.Air pollution control system and air pollution control method [P]. US Patent, 8475750, 2013 | | [41] | Warren E M, Gayheart J W, Silva A A.Integrated sorbent injection and flue gas desulfurization system [P]. US Patent, 20150139882, 2015 | | [42] | Chen X F, Liu X H.Application of Mg(OH)2 in sulphur elimination for smoke gas[J]. Sea-Lake Salt Chem. Ind., 2006, 35: 34(陈向锋, 刘晓慧. 氢氧化镁在烟气脱硫中的应用[J]. 海湖盐与化工, 2006, 35: 34) | | [43] | Luo Z H.A survey of the use of chemical cleaning agents for domestic furnaces[J]. Petro. Chem. Equip. Technol., 1983, (4): 47(罗中惠. 国产炉用化学清灰剂的使用概况[J]. 炼油设备设计, 1983, (4): 47) | | [44] | Li B Q, Chen H W, Xu S R.A study on mechanism of removing fouling on boiler heating surface by chemical additive[J]. J. North China Electr. Power, 1996, 23: 39(李保庆, 陈鸿伟, 徐生荣. 清灰剂清灰机理研究[J]. 华北电力学院学报, 1996, 23: 39) | | [45] | Zhang D Y, Wu S C, Zhang D Z.A introduction of chemical cleaning of boiler[J]. Mech. Factory Des., 1982, (2): 27(张德炎, 吴树成, 张大中. 锅炉化学清灰简介[J]. 机械工厂设计, 1982, (2): 27)> | | [46] | Zhou L B, Bellville D J, Zbacnik E P.Process for simultaneous removal of carbon dioxide and sulfur oxides from flue gas [P]. WIPO Patent, WO/2011/016906, 2011 | | [47] | Wappel D, Joswig S, Khan A A, et al.The solubility of sulfur dioxide and carbon dioxide in an aqueous solution of potassium carbonate[J]. Int. J. Greenh. Gas Control, 2011, 5: 1454 | | [48] | Li J X, Guo X Z.Application of fuel oil additives in oil-fired boiler[J]. Saf. Health Environ., 2009, 9: 32(李金现, 郭希柱. 燃料油添加剂在燃油锅炉上的应用[J]. 安全、健康和环境, 2009, 9: 32) | | [49] | Muir R J.Detergent / anti-oxidant additives for fuels and lubricants[P]. US Patent, 7618467, 2009 | | [50] | Tu F B, Zhou J M, Li C S.Application of emulsified heavy oil combustion mixed with water and new heating-energy additive to boiler[J]. Ind. Heat., 2006, 35: 44(涂福炳, 周孑民, 李长寿. 一种掺水和新型热能素的重油乳化燃烧技术在锅炉上的应用[J]. 工业加热, 2006, 35: 44) | | [51] | Harada Y, Nakamori M, Uera H.Behavior of magnesium based additives injected into oil fired boilers for as a preventive measure against gas side corrosion[J]. Zairyo-to-Kankyo, 1985, 34: 240 | | [52] | Ma C H.Heavy oil emulsifying additive and emulsifying pipe should be popularized in industrial furnace[J]. Ind. Furnace, 1986, (3): 55(马承华. 重油乳化添加剂及乳化管应在工业炉上推广使用[J]. 工业炉, 1986, (3): 55) | | [53] | Zoschak R J, Bryers R W.An experimental investigation of fuel additives in a supercharged boiler[J]. J. Eng. Power, 1960, 82: 169 | | [54] | Harada Y, Kayano I.Prevention of external corrosion in oil firing boiler by additive injection methods[J]. Corros. Eng., 1970, 19: 183 | | [55] | Zhai S M, Shang D Z, Zhao B C.Research on type SMH (II) additive in oil-fired utility boilers[J]. Power Eng., 1995, 15: 51(翟淑敏, 尚德镇, 赵宝成. 电站锅炉采用SMH(II)型燃油添加剂的研究[J]. 动力工程, 1995, 15: 51) | | [56] | Barreras F, Barroso J.Behavior of a high-capacity steam boiler using heavy fuel oil Part II: Cold-end corrosion[J]. Fuel Proc. Technol., 2004, 86: 107 | | [57] | Zhao C Y, Huang M F, Sun Y, et al.SMH II type additive for utility oil-fired boilers[J]. Power Eng., 1994, 14: 54(赵昌裕, 黄梅芬, 孙瑛等. SMH(II)型电站锅炉燃油添加剂[J]. 动力工程, 1994, 14: 54) | | [58] | Ma P Y, Qiu X Q, Duan X L.A feasibility study on emulsified heavy oil as a fuel for civil boiler[J]. Ind. Heat., 2005, 34: 56(马培勇, 仇性启, 段希利. 乳化重油作民用锅炉燃料可行性研究[J]. 工业加热, 2005, 34: 56) | | [59] | Collins J H, Lin M J L, Kekish G T. Stable oil dispersible magnesium hydroxide slurries [P]. US Patent, 4412844, 1983 | | [60] | Xu Y P.Application of EC-2(F) additive in oil-fired boiler[J]. Petrochem. Ind. Technol., 2001, 8: 36(徐云平. EC-2(F)燃油增效剂在燃油锅炉上的试验研究[J]. 石化技术, 2001, 8: 36) | | [61] | Chen Z L, Chen Z Y, Li S G.Industrial assessment and discussion on application of sayvol EC-2(F) fuel treatment in power plant boilers[J]. Power Eng., 1999, 19: 367(陈振林, 陈子怡, 李社桂. EC-2(F)燃油增效剂在电站锅炉上的应用考核结果与探讨[J]. 动力工程, 1999, 19: 367) | | [62] | Liu M, Wen X Y, Chen H F, et al.Heavy oil-fired gas turbine combustion test with the heavy oil being admixed with sayvol-EC2 all-purpose fuel oil synergist[J]. J. Eng. Therm. Energy Power, 1999, (2): 113(刘敏, 闻雪友, 陈洪发等. SAYVOL-EC2燃油全能增效剂掺入重油在燃气轮机上的燃烧试验[J]. 热能动力工程, 1999, (2): 113) | | [63] | Liu W S, Weng S Y, Zhao H, et al.Test and research concerning three kinds of additives used to oil-fired boilers[J]. Therm. Power Gener., 2003, (6): 18)(刘文胜, 翁善勇, 赵虹等. 3种添加剂在燃油锅炉上的试验研究[J]. 热力发电, 2003, (6): 18) | | [64] | Zhang X F, Gu X F, Sha J.A high efficient additive for catalyzing combustion of heavy fuel oil[J]. J. Fudan Univ.(Nat. Sci.), 2003, 42: 302(张信芳, 顾先锋, 沙金. 一种高效重质燃料油催化燃烧添加剂[J]. 复旦学报(自然科学版), 2003, 42: 302) | | [65] | Poullikkas A.Cost-benefit analysis for the use of additives in heavy fuel oil fired boilers[J]. Energy Convers. Manage., 2004, 45: 1725 | | [66] | Xiong X C.Application of metabolic engineering in biological desulphurization [D]. Beijing: Institute of Process Engineering, Chinese Academy of Sciences, 2008(熊小超. 代谢工程在生物脱硫中的应用 [D]. 北京: 中国科学院过程工程研究所, 2008) | | [67] | Liu J.Study on microbial catalytic desulfurization of fuel oil [D]. Tianjin: Nankai University, 2002(刘健. 燃料油微生物催化脱硫的研究 [D]. 天津: 南开大学, 2002) | | [68] | Jiang R F, Zhang A Y, Yin H C.Research of combusting test of the fuel additive on oil boiler[J]. Energy Conserv., 2003, (6): 8(蒋日富, 张爱友, 尹洪超. 燃油锅炉燃油生化添加剂试验研究[J]. 节能, 2003, (6): 8) |
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