Progress in Characterization of Metallic Materials Corrosion by Ultraviolet Photoelectron Spectroscopy and X-ray Photoelectron Spectroscopy

doi:10.11902/1005.4537.2016.096

Journal of Chinese Society for Corrosion and protection

2016, Vol. 36

Issue (4): 287-294 DOI: 10.11902/1005.4537.2016.096

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Progress in Characterization of Metallic Materials Corrosion by Ultraviolet Photoelectron Spectroscopy and X-ray Photoelectron Spectroscopy

Shenggang WANG(

),Miao SUN,Kang LONG

Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

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Abstract

In fact, the metallic material corrosion process may intrinsically involve subprocesses such as the exchange of valence electron between metallic atoms and ions in corrosive medium, the formation of oxide scale, the migration of corrosive species through the formed oxide scale, and the interaction between oxidation scale and corrosive medium. Therefore, the energy state of the valence electron of components of metallic material may play an important role in the corrosion process, thus for reveal which, ultraviolet photoelectron spectroscope (UPS) and X-ray photoelectron spectroscope (XPS) may become useful tool. Herewith new progress in this respect is subsequently introduced. The valence electron energy state of components for bulk nanocrystalline materials 304 stainless steel (BN-SS304), industrial pure aluminum (BN-Al) and ingot iron (BNII), as well as their counterparts of conventional microcrystalline ones (CP-SS304), (CP-Al) and (CPII) was characterized by UPS at room temperature. The valence electron energy state of components of the oxide scale formed on these metallic materials due to corrosion in hydrochloric acid solutions, and the oxide scales formed on BN-SS304 and CP-SS304 due to air oxidation at 900 ℃ were comparatively studied by XPS. The above aquired results may enable one to establish the relationship between the corrosion performance with the valence electron energy state of components of these metallic materials, and to figure the electron structure of components of the corresponding formed oxide scales, as well. Furthermore, a new concept of intrinsic parameter related with metallic material corrosion was proposed.

Key words: corrosion valence electron structure oxide scale XPS UPS

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	Shenggang WANG
	Miao SUN
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Shenggang WANG, Miao SUN, Kang LONG. Progress in Characterization of Metallic Materials Corrosion by Ultraviolet Photoelectron Spectroscopy and X-ray Photoelectron Spectroscopy. Journal of Chinese Society for Corrosion and protection, 2016, 36(4): 287-294.

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https://www.jcscp.org/EN/10.11902/1005.4537.2016.096 OR https://www.jcscp.org/EN/Y2016/V36/I4/287

Fig.1 Ultraviolet photoelectron spectroscopies of BNII (a) and CPII (b)^[14]

Fig.2 Ultraviolet photoelectron spectroscopies of BN-SS304 (a) and CP-SS304 (b) (SE: secondary electron)^[15]

Fig.3 Ultraviolet photoelectron spectroscopies of BN-Al (a) and CP-Al (b)^[16]

Fig.4 SEM images of corroded surfaces of BN-SS304 (a) and CP-SS304 (b) after 30 d immersion in 0.5 mol/L HCl solution at room temperature^[15]

Fig.5 SEM images of corroded surfaces of BN-Al (a) and CP-Al (b) after 9 d immersion in 0.25 mol/L HCl solution at room temperature^[16]

Fig.6 Binding energy (a) and atomic fraction (b) of Cl^- in the oxide films formed on of BN-SS304 and CP-SS304 after 30 d immersion in 0.5 mol/L HCl solution at room temperature^[15]

Fig.7 Binding energy (a) and atomic fraction (b) of Cl^- in the oxide films formed on BN-Al and CP-Al after 9 d immersion in 0.25 mol/L HCl solution at room temperature^[16]

Fig.8 Oxidation kinetics curves of BN-SS304 and CP-SS304 during heating stage from 25 ℃ to 900 ℃ (a) and isothermal oxidation at 900 ℃ (b) in air^[17]

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