用XPS、FT-IR及Raman光谱研究ATMP-Fe配合物膜

中国腐蚀与防护学报

1992, Vol. 12

Issue (4): 308-314

研究报告

本期目录 | 过刊浏览

用XPS、FT-IR及Raman光谱研究ATMP-Fe配合物膜

方景礼;李莹;叶向荣;王占文

南京大学;南京化工学院;南京大学;南京化工学院

XPS, FT-IR AND RAMAN SPECTRUM STUDIES OF ATMP-Fe COORDINATION COMPOUND FILM

Fang Jinli~1; Li Ying~2; Ye Xiangrong~1 and Wang Zhanwen~2 1(Nanjing University) 2(Nanjing Institute of Chemical Technology)

全文: PDF(477 KB)

摘要: 采用XPS、FT-FR、及Raman光谱研究了经氨基三甲叉膦酸(ATMP)处理的钢铁表面所形成的表面膜。结果表明ATMP在铁表面上形成了一种耐蚀的配合物膜。结合Ar~+溅射剥蚀技术,测定了不同深度膜层的组成。在元素组成近似恒定区测得膜的相对原子浓度(A.C.％)为:O48.4％P28.6％;Fe 7.0％;N 4.3％;C 11.7％。由此推断其结构单元组成为[Fe(ATMP)_2]。

Abstract：The protective surface film formed of carbon steel after a treatment in 1.0 mol/L amino-trimethylidenephosphonic acid(ATMP) solution was analysed by XPS, FT-IR and Raman spectrometer. The restlts showed that an anticorrosive coordination compound film was formed on the steel surface. By Ar~+ sputtering, the composition depth profile of the film was determind. The relative atomic percent contents(A. C. ％) of the film, as obtained from the element composition constant region of the profile curves, were 48.4％O; 28.6％P; 7.0％Fe; 4.3％N; 11.7％C. The structure of the coordination compound film was deducted from the above results, as probably [Fe(ATMP)_2]_n.

收稿日期: 1992-08-25

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	方景礼
	李莹
	叶向荣
	王占文
44.8K

引用本文:

方景礼;李莹;叶向荣;王占文. 用XPS、FT-IR及Raman光谱研究ATMP-Fe配合物膜[J]. 中国腐蚀与防护学报, 1992, 12(4): 308-314.
. XPS, FT-IR AND RAMAN SPECTRUM STUDIES OF ATMP-Fe COORDINATION COMPOUND FILM. J Chin Soc Corr Pro, 1992, 12(4): 308-314.

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y1992/V12/I4/308

[1] Michel.D.,Corrosion,37(5) .262(1989)
[2] Eur.Plat..1O.485
[3] U.S,Pat.4． 276． 089． 4,409,121,4,717,541
[4] 方景礼,石油化工.(7) .422(1980)
[5] Fang Jingli.Wu Naijun.Wang zhanwen.Li Ying,Corrosion,47(3) ,169(1991) ;应用化学.7(2) .9(1990)
[6] Fang Jingli.Cai zi,Plat.&.Surf.Finist..77(2) ,58(1988)
[7] Fang Jingli.Wu Naijun.Plat.&.Surf.Finist.,77(2) ,54(1990)
[8] 方景礼,李莹,叶向荣,王占文,表面技术,(4) ,12(1991)
[9] F.R.G.Standard Din 50,942(1970)
[10] Weber.J.Prace Inst.Mech.Precyz.,l6． 19(1956)
[11] B..A.A.,19,2119(1988)
[12] Carter.R.P.,Inorg.Chem.,6． 393(1967)
[13] Smith.T.D.J.,Inorg.Nucl.Chem.,9,150(1959)
[14] Moedritzer.K..Syn.Inorg.Metal-org.Chem.,2(4) ,137(1972)
[15] Goggjn.P.L..Woodwand.L.A.,Trans Faraday Soc.58,1495(1962)

No related articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed