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中国腐蚀与防护学报  2017, Vol. 37 Issue (6): 513-518    DOI: 10.11902/1005.4537.2016.225
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食品包装用镀锡薄钢板的腐蚀机理研究进展
夏大海1,2(), 宋诗哲1,2, 王吉会1(), 高志明1, 胡文彬1
1 天津大学材料科学与工程学院 天津市材料复合与功能化重点实验室 天津 300350
2 中国科学院金属研究所 中国科学院核用材料与安全评价重点实验室 沈阳 110016
Research Progress on Corrosion Mechanism of Tinned Steel Sheet Used for Food Parkaging
Dahai XIA1,2(), Shizhe SONG1,2, Jihui WANG1(), Zhimng GAO1, Wenbin HU1
1 Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China
2 CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
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摘要: 

镀锡薄钢板由于高强度、高阻隔性及优越的加工使用性能,在食品包装材料中占有非常重要的地位,当内容物腐蚀性较强时,其缺点之一是会发生腐蚀失效。本文综述了食品环境中镀锡薄钢板的腐蚀行为,探讨了食品包装用镀锡薄钢板和有机涂层涂覆的镀锡薄钢板的腐蚀机理。镀锡薄钢板的腐蚀过程与内容物pH值、溶解氧含量以及腐蚀性离子种类密切相关。可为镀锡薄钢板采取合适的表面处理措施以及设计新型有机涂层材料提供科学依据。

关键词 金属包装镀锡薄钢板腐蚀机理    
Abstract

Tinned steel sheet is one of the most frequently used metal packaging materials for food industry, due to its high strength, good barrier property, and excellent processing performance. However, one shortcoming related with the application of tinned steel sheet is the trouble of corrosion, peculiarly when the stored food is highly corrosive. Therefore, the corrosion behavior of tinned steel in food environment as well as the relevant corrosion mechanism of the bare- and lacquered-tinned steel are introduced and discussed in the paper. It seems that the corrosion process was closely linked to pH value, dissolved oxygen and some corrosive ions in the food-containing electrolyte. It is noted that new surface treatment methods and new organic coatings for the tinned steel sheet are needed to develop. Finally, the future work on this topic is also pointed out.

Key wordsmetal packaging    tinned steel sheet    corrosion mechanism
收稿日期: 2016-11-24     
ZTFLH:  TG172.3  
基金资助:国家自然科学基金 (51701140和51471117) 和天津市自然科学基金 (14JCYBJC17700)
作者简介:

作者简介 夏大海,男,1984年生,讲师

引用本文:

夏大海, 宋诗哲, 王吉会, 高志明, 胡文彬. 食品包装用镀锡薄钢板的腐蚀机理研究进展[J]. 中国腐蚀与防护学报, 2017, 37(6): 513-518.
Dahai XIA, Shizhe SONG, Jihui WANG, Zhimng GAO, Wenbin HU. Research Progress on Corrosion Mechanism of Tinned Steel Sheet Used for Food Parkaging. Journal of Chinese Society for Corrosion and protection, 2017, 37(6): 513-518.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.225      或      https://www.jcscp.org/CN/Y2017/V37/I6/513

图1  镀锡薄钢板在0.5 mol/L NaCl溶液中浸泡前后的截面形貌以及EDS元素线扫描结果[14]
图2  镀锡薄钢板在0.5 mol/L NaCl溶液中的腐蚀机制示意图[14]
图3  涂覆涂层的镀锡薄钢板在某功能饮料中浸泡364 d后的表面形貌[22]
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