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中国腐蚀与防护学报  2017, Vol. 37 Issue (6): 504-512    DOI: 10.11902/1005.4537.2016.209
  综合评述 本期目录 | 过刊浏览 |
油气管材应力诱导腐蚀电化学行为探讨
鲍明昱1, 任呈强1,2(), 胡静思1, 刘博1, 李佳蒙1, 王丰1, 刘丽1, 郭小阳2
1 西南石油大学材料科学与工程学院 成都 610500
2 西南石油大学 油气藏地质及开发工程国家重点实验室 成都 610500
Stress Induced Corrosion Electrochemical Behavior of Steels for Oil and Gas Pipes
Mingyu BAO1, Chengqiang REN1,2(), Jingsi HU1, Bo LIU1, Jiameng LI1, Feng WANG1, Li LIU1, Xiaoyang GUO2
1 School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China
2 State Key Laboratory of Oil & Gas Reservoir Geology and Exploration, Southwest Petroleum University, Chengdu 610500, China;
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摘要: 

就近年来人们对油气管材应力诱导腐蚀电化学行为的研究进行了评述,分析了应力诱导对油气管材腐蚀热力学、腐蚀动力学和腐蚀产物膜的影响,并对该领域未来的研究方向进行了展望。

关键词 油气管材应力诱导腐蚀电化学腐蚀产物膜原位技术    
Abstract

In the oil and gas industry, the effect of stress on corrosion of steels for pipes can not be ignored due to the environment of complex corrosive media and the applied multiple stress loads on pipes during service. The synergistic effect of stress and corrosive medium can not only cause stress corrosion cracking of oil and gas pipes, but also influence corrosion behavior of steels for oil and gas pipes by changing their electrochemical process. Therefore, the research on the stress induced corrosion electrochemical behavior of steels for oil and gas pipes was commented in this paper. The effect of stress on corrosion thermodynamics, corrosion kinetics and corrosion product film of steels for oil and gas pipes was analyzed. At last, the research trend of the stress influenced corrosion electrochemical behavior of steels for oil and gas pipes was discussed.

Key wordsoil and gas pipe    stress induced corrosion    electrochemistry    corrosion product film,    in situ technology
收稿日期: 2016-10-25     
ZTFLH:  TG172  
基金资助:国家自然科学基金 (51374180)
作者简介:

作者简介 鲍明昱,男,1989年生,博士生

引用本文:

鲍明昱, 任呈强, 胡静思, 刘博, 李佳蒙, 王丰, 刘丽, 郭小阳. 油气管材应力诱导腐蚀电化学行为探讨[J]. 中国腐蚀与防护学报, 2017, 37(6): 504-512.
Mingyu BAO, Chengqiang REN, Jingsi HU, Bo LIU, Jiameng LI, Feng WANG, Li LIU, Xiaoyang GUO. Stress Induced Corrosion Electrochemical Behavior of Steels for Oil and Gas Pipes. Journal of Chinese Society for Corrosion and protection, 2017, 37(6): 504-512.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.209      或      https://www.jcscp.org/CN/Y2017/V37/I6/504

图1  应力对钢材开路电位的影响 (低于屈服强度)[20,21]
图2  拉应力对P110钢开路电位的影响[23]
图3  塑性应变对16MnR钢开路电位的影响[24]
图4  不同拉应力条件下P110钢的腐蚀电流密度[23]
图5  不同拉应力条件下P110钢的Evans极化图[23]
Group Applied stress Corrosion rate / mma-1
1 0 0.3005
2 30%σs 0.3036
3 70%σs 0.3333
4 90%σs 0.3724
表1  不同拉应力作用下试样的腐蚀速率[40]
图6  L80钢级套管材料的失重法腐蚀实验结果[34]
图7  拉应力对X80钢腐蚀产物膜表面形貌的影响[20]
图8  压应力对HP13Cr钢腐蚀产物膜表面形貌的影响[35]
[1] Li J P, Zhao G X, Wang Y, et al.Static corrosion of oil thimble used in Tarim oil field[J]. J. Chin. Soc. Corros. Prot., 2004, 24: 230(李建平, 赵国仙, 王玉等. 塔里木油田用油套管钢的静态腐蚀研究[J]. 中国腐蚀与防护学报, 2004, 24: 230)
[2] Zhu S D, Li J L, Yang Z G, et al.Effect of temperature on CO2 corrosion behavior of J55 tubing[J]. Mater. Mech. Eng., 2014, 38(8): 6(朱世东, 李金灵, 杨志刚等. 温度对J55油管CO2腐蚀行为的影响[J]. 机械工程材料, 2014, 38(8): 6)
[3] Xu N, Jiang Z Y.Application of nationalized high strength steel X70 for Sichuan to East gas transmission pipeline[J]. Pet. Eng. Constr., 2009, 35(S1): 1(许宁, 姜志阳. 川气东送X70高强度钢级管道材料的国产化应用[J]. 石油工程建设, 2009, 35(S1): 1)
[4] Wang Y, Yu H Y, Cheng Y, et al.Corrosion behaviors of X80 steel in typical soil environment along the second west-east gas pipeline[J]. Corros. Prot., 2012, 33: 1060(王莹, 俞宏英, 程远等. X80钢在西气东输二线典型土壤中的腐蚀行为[J]. 腐蚀与防护, 2012, 33: 1060)
[5] Bao M Y, Ren C Q, Zheng Y P, et al.Adaptability evaluation of 316L stainless steel based on pitting corrosion in acid gas field[J]. Mater. Rev., 2016, 30(17): 10(鲍明昱, 任呈强, 郑云萍等. 基于点蚀的316L不锈钢在酸性气田环境中的适应性评价[J]. 材料导报, 2016, 30(17): 10)
[6] Yang D M, Li Y G.Internal corrosion analysis and material selection of gas gathering lines in the Yakela Gas Field, Southwest Tarim Basin[J]. Nat. Gas Ind., 2012, 32(10): 74(羊东明, 李亚光. 雅克拉气田集气管线内腐蚀分析及材质选用[J]. 天然气工业, 2012, 32(10): 74)
[7] Xia Z, Chou K C, Szklarska-Smialowska Z.Pitting corrosion of carbon steel in CO2-containing NaCl brine[J]. Corrosion, 1989, 45(8): 636
[8] Zhu S D, Wei J F, Bai Z Q, et al.Failure analysis of P110 tubing string in the ultra-deep oil well[J]. Eng. Fail. Anal., 2011, 18: 950
[9] Li B, Ren C Q, Liu L, et al.Research on the kinetics of CO2 corrosion on N80 steel[J]. Mater. Rev., 2013, 27: 116(李波, 任呈强, 刘丽等. N80钢的CO2腐蚀动力学研究[J]. 材料导报, 2013, 27: 116)
[10] Ren C Q, Liu D X, Bai Z Q, et al.Corrosion behavior of oil tube steel in simulant solution with hydrogen sulfide and carbon dioxide[J]. Mater. Chem. Phys., 2005, 93: 305
[11] Zou H L, Yao F, Wen X H, et al.Research on dynamic corrosion rate and influence of anion concentration under high temperature and high pressure[J]. Contemp. Chem. Ind., 2016, 45: 241(邹洪岚, 姚飞, 温晓红等. 高温高压动态腐蚀速率及阴离子浓度影响研究[J]. 当代化工, 2016, 45: 241)
[12] Liang P, Li X G, Du C W, et al.Evaluation of soil factors influencing corrosion of buried X70 pipeline steel[J]. Corros. Prot., 2009, 30: 526(梁平, 李晓刚, 杜翠薇等. 影响埋地X70管线钢腐蚀性的土壤因素评价[J]. 腐蚀与防护, 2009, 30: 526)
[13] Song B Q, Chen X, Ma G Y, et al.Effect of SRB on corrosion behavior of X70 pipeline steel in near-neutral pH solution[J]. J. Chin. Soc. Corros. Prot., 2016, 36: 212(宋博强, 陈旭, 马贵阳等. SRB对X70管线钢在近中性pH溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2016, 36: 212)
[14] Qu S Y, Hou J R, Cui M W, et al.Corrosion of X70 steel under multi-phase flow[J]. Oil Gas Storage Transport., 2016, 35: 536(曲世元, 侯吉瑞, 崔铭伟等. 多相流动对X70钢腐蚀行为的影响[J]. 油气储运, 2016, 35: 536)
[15] Raja V S, Shoji T.Stress corrosion cracking: Theory and practice [M]. Britain: Woodhead Publishing Limited, 2011
[16] Li M C, Cheng Y F.Corrosion of the stressed pipe steel in carbonate-bicarbonate solution studied by scanning localized electroche-mical impedance spectroscopy[J]. Electrochim. Acta, 2008, 53: 2831
[17] Gao K, Li D, Pang X, et al.Corrosion behaviour of low-carbon bainitic steel under a constant elastic load[J]. Corros. Sci., 2010, 52: 3428
[18] Gutman E M.Mechanochemistry and Corrosion Protection of Metal [M]. Beijing: Science Press, 1989(古特曼. 金属力学化学与腐蚀防护 [M]. 北京: 科学出版社, 1989)
[19] Chen X, He C, Liu S, et al.Effect of stress on corrosion behavior of X70 steel in NaHCO3 solution[J]. J. Petrochem. Univ., 2011, 24(5): 69(陈旭, 何川, 刘硕等. 应力对X70钢在NaHCO3溶液中腐蚀行为的影响[J]. 石油化工高等学校学报, 2011, 24(5): 69)
[20] Zhang J, Liu J, Hu Q, et al.The influence of tensile stress on the electrochemical behavior of X80 steel in a simulated acid soil solution[J]. Anti-Corros. Method Mater., 2015, 62: 103
[21] Ren R K, Zhang S, Pang X L, et al.A novel observation of the interaction between the macroelastic stress and electrochemical corrosion of low carbon steel in 3.5 wt% NaCl solution[J]. Electrochim. Acta, 2012, 85: 283
[22] Ren C Q, Zeng D Z, Lin J H, et al.Sour corrosion of C110 steel and its influence by galvanic couple and stress[J]. Ind. Eng. Chem. Res., 2012, 51: 4894
[23] Bao M Y, Ren C Q, Lei M Y, et al.Electrochemical behavior of tensile stressed P110 steel in CO2 environment[J]. Corros. Sci., 2016, 112: 585
[24] Sun J B, Liu W, Lu M X.Electrochemical corrosion behavior of 16MnR steel with plastic strain in CO2 environment[J]. J. Mater. Eng., 2009, (1): 59(孙建波, 柳伟, 路民旭. 塑性变形条件下16MnR钢的CO2腐蚀电化学行为[J]. 材料工程, 2009, (1): 59)
[25] Herring C.The use of classical macroscopic concepts in surface energy problems [A]. Gomer R, Smith C S, eds. Structure and Properties of Solid Surfaces 1953 [C]. Chicago, Illinois: University of Chicago Press, 1953
[26] Li J F, Chen W J, Zhao X S, et al.Corrosion behavior of 2195 and 1420 Al-Li alloys in neutral 3.5%NaCl solution under tensile stress[J]. Trans. Nonferrous Met. Soc., 2006, 16: 1171
[27] Yang W J, Yang P, Li X M, et al.Influence of tensile stress on corrosion behaviour of high-strength galvanized steel bridge wires in simulated acid rain[J]. Mater. Corros., 2012, 63: 401
[28] Li J B, Hou X, Zheng M S, et al.Joint effect of temperature, stress states and sulfur ions on the CO2 corrosion behavior of N80 tubing steel[J]. Int. J. Electrochem. Sci., 2007, 2: 607
[29] Zhang G A, Cheng Y F.Micro-electrochemical characterization of corrosion of pre-cracked X70 pipeline steel in a concentrated carbonate/bicarbonate solution[J]. Corros. Sci., 2010, 52: 960
[30] Li D G, Feng Y R, Bai Z Q, et al.Investigation on CO2 corrosion behaviors of N80 tubing steel under stress conditions[J]. Acta Chim. Sin., 2007, 65: 1807(李党国, 冯耀荣, 白真权等. N80油套管钢应力状态下的CO2腐蚀行为研究[J]. 化学学报, 2007, 65: 1807)
[31] Xia M X, Zheng H X, Yuan S, et al.Recrystallization of preformed AZ91D magnesium alloys in the semisolid state[J]. Mater. Des., 2005, 26: 343
[32] Despic A R, Raicheff R G, Bockris J O M. Mechanism of the acceleration of the electrodic dissolution of metals during yielding under stress[J]. J. Chem. Phys., 1968, 49: 926
[33] Liu Q Y, Li H P.Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress[J]. Int. J. Miner. Process., 2011, 98: 82
[34] Wang X H, Yin C X, Wang J D.Influence of compressive stress on corrosion of premium connection casing material[J]. J. Chin. Univ. Pet.(Ed. Nat. Sci.), 2013, 37: 119(王新虎, 尹成先, 王建东. 压应力对特殊螺纹套管材料腐蚀的影响[J]. 中国石油大学学报(自然科学版), 2013, 37: 119)
[35] Yin C X, Wang X H, Zhao X H, et al.Influence of compressive stress on electrochemical corrosion behavior of HP13Cr tubing steel[J]. Mater. Prot., 2014, 47(9): 29(尹成先, 王新虎, 赵雪会等. 压应力对HP13Cr钢电化学腐蚀性能的影响[J]. 材料保护, 2014, 47(9): 29)
[36] Gu C Y, Di Q F, Wang Z H, et al.Corrosion mechanism of casing under tensile stress in oil/gas well[J]. Drill. Prod. Technol., 2007, 30(1): 84(顾春元, 狄勤丰, 王掌洪等. 拉应力条件下油气井套管腐蚀机理研究[J]. 钻采工艺, 2007, 30(1): 84)
[37] Chu W Y, Ma R T, Hsiao C M.Technical note: Stress corrosion cracking of mild steel under compressive stress[J]. Corrosion, 1987, 43: 251
[38] Hou D, Zeng D Z, Chen Y X, et al.Determination of stress-corrosion rate of 110 ksi steel casings Pl10 and C110 under acidic oilfield environment containing hydrogen sulfide and carbon dioxide[J]. Mater. Prot., 2014, 47(10): 65(侯铎, 曾德智, 陈玉祥等. H2S, CO2酸性环境中110ksi钢P110, C110套管的应力腐蚀速率[J]. 材料保护, 2014, 47(10): 65)
[39] Wang F, Wang L X, Liu Z Y, et al.Study on stress corrosion behavior of TP110TS oil pipeline steel in the sour gas field environment[J]. Surf. Technol., 2015, 44(3): 57(王峰, 王立贤, 刘智勇等. TP110TS油管钢在酸性气田环境中的应力腐蚀行为研究[J]. 表面技术, 2015, 44(3): 57)
[40] Zhao Z X, Gao D L, Wang Z L.Experimental study about the effect of stress loading on corrosion rate of TP110TS tube steel in corrosive environment with high H2S concentration[J]. Drill. Prod. Technol., 2011, 34(1): 59(赵增新, 高德利, 王梓力. 应力加载对TP110TS管钢在高含H2S腐蚀条件下腐蚀速率影响的实验研究[J]. 钻采工艺, 2011, 34(1): 59)
[41] Huang H C, Shen Z H, Gao D L.Stress corrosion of casing in "Three high" gas field and anti-corrosion design[J]. Chin. Pet. Mach., 2015, 43(3): 6(黄洪春, 沈忠厚, 高德利. 三高气田套管应力腐蚀与防腐设计研究[J]. 石油机械, 2015, 43(3): 6)
[42] Xu L Y, Cheng Y F.An experimental investigation of corrosion of X100 pipeline steel under uniaxial elastic stress in a near-neutral pH solution[J]. Corros. Sci., 2012, 59: 103
[43] Svenningsen G, Palencsár A, Kvarekv? J.Investigation of iron sulfide surface layer growth in aqueous H2S/CO2 environments [A]. Corrosion 2009[C]. Atlanta, Georgia: NACE International, 2009
[44] Zhang G A, Cheng Y F.Micro-electrochemical characterization and Mott-Schottky analysis of corrosion of welded X70 pipeline steel in carbonate/bicarbonate solution[J]. Electrochim. Acta, 2009, 55: 316
[45] Mu L J, Zhao W Z.Effect of pre-strain states on electronic property of passive film on J55 pipeline steel in Changqing oilfield Luo-he stratum water[J]. J. Chin. Soc. Corros. Prot., 2010, 30: 491(慕立俊, 赵文轸. 预应变状态对J55油套管钢在长庆油田地下洛河水中腐蚀电化学性能的影响[J]. 中国腐蚀与防护学报, 2010, 30: 491)
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