稀土 (Y,La,Ce) 复合添加对Ni-10Cr-5Al合金在1000 ℃下高温氧化行为的影响

doi:10.11902/1005.4537.2016.129

中国腐蚀与防护学报

2016, Vol. 36

Issue (5): 489-496 DOI: 10.11902/1005.4537.2016.129

本期目录 | 过刊浏览

稀土 (Y,La,Ce) 复合添加对Ni-10Cr-5Al合金在1000 ℃下高温氧化行为的影响

黄嘉鹏¹,杨斌²,汪航²(

)

1. 江西理工大学材料科学与工程学院赣州 341000
2. 江西理工大学工程研究院赣州 341000

Effect of Multiple Addition of Y, La and Ce on Oxidation Behavior of Ni-10Cr-5Al Alloy at 1000 ℃ in Air

Jiapeng HUANG¹,Bin YANG²,Hang WANG²(

)

1. School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
2. Institute of Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

全文: PDF(6450 KB) HTML

摘要:

通过真空感应熔炼以单一和复合两种方式在Ni-10Cr-5Al合金中添加1% (质量分数) 的稀土Y,La,Ce,Y+La,Y+Ce以及La+Ce。研究了不同稀土元素添加类型对Ni-10Cr-5Al合金在1000 ℃下空气中氧化行为的影响。采用热重法并结合X射线衍射、扫描电子显微镜、能谱仪等分析手段,检测了合金氧化后的微观结构演变和元素分布,进而探讨了不同稀土添加类型的影响作用。结果表明：经1000 ℃氧化200 h后,不同合金的稳态氧化过程均服从抛物线规律;合金添加稀土后,虽然只有单一添加Y对合金的抗氧化性能有所提高,而其他添加方式均增大了合金的氧化速率,其中复合添加的方式加剧了合金沿晶界的内氧化,但添加稀土可以抑制θ-Al₂O₃向α-Al₂O₃的转变,有利于提高合金氧化膜的抗剥落性能。

关键词 ： NiCrAl合金, 稀土元素, 活性元素效应, 高温氧化

Abstract：

Ni-10Cr-5Al alloys with addition of 1%(mass fraction) of Y, La, Ce, Y+La, Y+Ce and La+Ce respectively, were prepared by vacuum induction melting. Then their oxidation behavior in air at 1000 ℃ was studied by means of thermogravimetric analysis, X-ray diffraction and scanning electron microscope with energy dispersive spectroscope. The results indicated that the oxidation kinetics of the alloys with addition of different rare earth elements at 1000 ℃ obeyed the parabolic law; however only the single addition of Y could decrease the oxidation rate of Ni-10Cr-5Al alloy, but the addition of all others increased the oxidation rate of the alloys. The multiple additions of rare earth elements could promote the internal oxidation of the alloys along grain boundaries. Besides, the transformation of θ-Al₂O₃ to α-Al₂O₃ of the formed oxide scales is suppressed in alloys containing rare earths, which will beneficial to improve the adhesion of the oxide scale.

Key words： NiCrAl alloy rare earth element reactive element effect high temperature oxidation

基金资助:国家自然科学基金项目 (51401095),江西省科技厅留学归国人员扶助计划项目 (20161BBH80030)和江西理工大学博士启动基金项目 (jxxjbs15001) 资助

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	黄嘉鹏
	杨斌
	汪航
44.8K

引用本文:

黄嘉鹏,杨斌,汪航. 稀土 (Y,La,Ce) 复合添加对Ni-10Cr-5Al合金在1000 ℃下高温氧化行为的影响[J]. 中国腐蚀与防护学报, 2016, 36(5): 489-496.
Jiapeng HUANG, Bin YANG, Hang WANG. Effect of Multiple Addition of Y, La and Ce on Oxidation Behavior of Ni-10Cr-5Al Alloy at 1000 ℃ in Air. Journal of Chinese Society for Corrosion and protection, 2016, 36(5): 489-496.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.129 或 https://www.jcscp.org/CN/Y2016/V36/I5/489

图1 添加不同稀土元素的Ni-10Cr-5Al合金在1000 ℃下空气中氧化200 h的动力学曲线

表1 合金试样的氧化速率常数kp

图2 添加不同稀土元素的Ni-10Cr-5Al合金氧化增重的平方与时间的关系曲线

图3 添加不同稀土元素的试样在1000 ℃下氧化200 h后表面的XRD谱

图4 添加不同稀土元素的合金试样在1000 ℃下氧化200 h后的表面形貌

表2 添加不同稀土元素的试样在1000 ℃氧化200 h后表面的相组成

图5 添加不同稀土元素的合金试样在1000 ℃下空气中氧化200 h后截面的SEM像

[1]	Shi C X, Zhong Z Y.Development and innovation of superalloy in China[J]. Acta Metall. Sin., 2010, 46(11): 1281
[1]	(师昌绪, 仲增墉. 我国高温合金的发展与创新[J]. 金属学报, 2010, 46(11): 1281)
[2]	Reed R C.The Superalloys Fundamentals and Applications [M]. Cambridge: Cambridge University Press, 2006: 5
[3]	Peng X, Wang F.High-temperature Oxidation of Aerospace Materials. In: Zhang S, Zhao D L, eds. Aerospace Materials Handbook [M]. Boca Raton: CRC Press, 2012: 237
[4]	Geddes B, Leon H, Huang X.Superalloys: Alloying and Performance[M]. Washington: ASM International, 2010: 59
[5]	Stringer J.The reactive element effect in high-temperature corrosion[J]. Mater. Sci. Eng., 1989, A120: 129
[6]	Xu K D, Ren Z M, Li C J.Progress in application of rare metals in super alloys[J]. Rare Met., 2014, 33(2) : 111
[7]	Li M S, Zhang Y M.A review on effect of reactive elements on oxidation of metals[J]. Corros. Sci. Prot. Technol., 2001, 13(6): 333
[7]	(李美栓, 张亚明. 活性元素对合金高温氧化的作用机制[J]. 腐蚀科学与防护技术, 2001, 13(6): 333)
[8]	Xiao C B, Han Y F.Effect of yttrium on high temperature oxidation behavior of Ni-Al-Mo-B alloy IC6[J]. J. Mater. Sci., 2001, 36(19): 4755
[9]	Shi Z X, Liu S Z, Han M, et al.Influence of yttrium addition on high temperature oxidation resistance of single crystal superalloy[J]. J. Rare Earths, 2013, 31(8): 795
[10]	Song L G, Li S S, Zheng Y R, et al.Effect of Y on high temperature oxidation resistance of a directionally solidified super alloy[J]. J. Rare Earths, 2004, 22(6): 794
[11]	Yu P, Yang L, Wang W.Effect of reactive element yttrium on oxidation behavior of K38 superalloy at 1000 ℃ in air[J]. J. Shenyang Univ. Chem. Technol., 2011, 25(3): 212
[11]	(于萍, 杨蕾, 王文. 不同含量的活性元素钇对K38高温合金1000 ℃氧化行为的影响[J]. 沈阳化工大学学报, 2011, 25(3):212)
[12]	Weng F, Yu H, Chen C, et al.High-temperature oxidation behavior of Ni-based superalloys with Nb and Y and the interface characteristics of oxidation scales[J]. Surf. Interface Anal., 2015, 47(3): 362
[13]	Li X L, He S M, Zhou X T, et al.Effects of rare earth yttrium on microstructure and properties of Ni-16Mo-7Cr-4Fe nickel-based super alloy[J]. Mater. Charact., 2014, 95: 171
[14]	Xiao X, Xu L, Qin X Z, et al.Effect of elements Y and Ce on high temperature oxidation behavior of directionally-solidified Ni-basedsuper alloy[J]. Chin. J. Nonferrous Met., 2014, 24(11): 2769
[14]	(肖旋, 徐乐, 秦学智等. 稀土元素Y和Ce对定向凝固镍基高温合金高温氧化行为的影响[J]. 中国有色金属学报, 2014, 24(11):2769)
[15]	Song X, Wang L, Liu Y, et al.Effects of temperature and rare earth content on oxidation resistance of Ni-based super alloy[J]. Prog. Nat. Sci. Mater. Int., 2011, 21(3): 227
[16]	Ul-Hamid A.TEM study of the effect of Y on the scale microstructures of Cr2O3- and Al2O3-forming alloys[J]. Oxid. Met., 2002, 58(1): 23
[17]	Ul-Hamid A.TEM study of scale microstructures formed on Ni-10Cr and Ni-10Cr-5Al alloys with and without Y addition[J]. Oxid. Met., 2002, 58(1): 41
[18]	Ramanathan L V.Role of rare-earth elements on high temperature oxidation behavior of Fe-Cr, Ni-Cr and Ni-Cr-Al alloys[J]. Corros. Sci., 1993, 35(5): 871
[19]	Wang W, Yu P, Wang F, et al.The effect of yttrium addition on the isothermal oxidation behavior of sputtered K38 nanocrystalline coating at 1273 K in air[J]. Surf. Coat. Technol., 2007, 201(16): 7425
[20]	Tawancy H M, Abbas N M.An analytical electron microscopy stu- dy of the role of La and Y during high-temperature oxidation of selected Ni-base alloys[J]. Scr. Metall. Mater., 1993, 29(5): 689
[21]	Chen S F, Ma H P, Ju Q, et al.Effect of rare earth element lanthanum on oxidation behavior of GH230 at 1000 ℃ in air[J]. J. Iron. Steel Res., 2009, 21(11): 45
[21]	(陈石富, 马惠萍, 鞠泉等. 稀土元素La对GH230合金1000 ℃抗氧化性能的影响[J]. 钢铁研究学报, 2009, 21(11): 45)
[22]	Zhang Y F, Zhu D M, Shores D A.Effect of yttrium on the oxidation behavior of cast Ni-30Cr alloy[J]. Acta Metall. Mater., 1995, 43(11): 4015
[23]	Nan H Q, Li J S, Hu R, et al.Effects of rare earth metal Ceadditions on the 1150 ℃ isothermal oxidation behavior of Ni-20Cr alloy[J]. Adv. Mater. Res., 2013, 771: 23
[24]	Ramanarayanan T A, Ayer R, Petkovic-Luton R, et al.The influence of yttrium on oxide scale growth and adherence[J]. Oxid. Met., 1988, 29(5): 445
[25]	Kuenzly J D, Douglass D L.The oxidation mechanism of Ni3Al containing yttrium[J]. Oxid. Met., 1974, 8(3): 139
[26]	Wang J, Yuan L, Hu R, et al.Effect of lanthanum on oxidation behavior of Ni-20Cr-18W-1Mo alloys at 1373 K for 100 h in air[J]. Rare Met. Mater. Eng., 2014, 43(9): 2060
[27]	Khanna A S, Wasserfuhr C, Quadakkers W J, et al.Addition of yttrium, cerium and hafnium to combat the deleterious effect of sulphur impurity during oxidation of an Ni-Cr-Al alloy[J]. Mater. Sci. Eng., 1989, A120: 185
[28]	Ford D A, Fullagar K P L, Bhangu H K, et al. Improved performance rhenium containing single crystal alloy turbine blades utilizing PPM levels of the highly reactive elements lanthanum and yttrium[J]. J. Eng. Gas Turbines Power, 1999, 121(1): 138
[29]	Cadoret Y, Monceau D, Bacos M P, et al.Effect of platinum on the growth rate of the oxide scale formed on cast nickel aluminide intermetallic alloys[J]. Oxid. Met., 2005, 64(4): 185

[1]	郑艳欣, 刘颖, 宋青松, 郑峰, 贾玉川, 韩培德. 含铁铜基陶瓷复合材料高温氧化行为与耐磨性研究[J]. 中国腐蚀与防护学报, 2020, 40(2): 191-198.
[2]	徐勋虎,何翠群,向军淮,王玲,张洪华,郑晓冬. Co-20Re-25Cr-1Si合金在0.1 MPa纯O₂中的高温氧化行为[J]. 中国腐蚀与防护学报, 2020, 40(1): 75-80.
[3]	夏俊捷,牛红志,刘敏,曹华珍,郑国渠,伍廉奎. 基于卤素效应的阳极氧化技术提高Ti48Al5Nb合金抗高温氧化性能[J]. 中国腐蚀与防护学报, 2019, 39(2): 96-105.
[4]	谢冬柏,周游宇,鲁金涛,王文,朱圣龙,王福会. Al/Si对镍基合金在超临界水中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2019, 39(1): 68-76.
[5]	王玲,向军淮,张洪华,覃宋林. 3种不同Cr含量Co-20Re-Cr合金在1000和1100 ℃的高温氧化行为[J]. 中国腐蚀与防护学报, 2019, 39(1): 83-88.
[6]	谢冬柏, 周游宇, 鲁金涛, 王文, 朱圣龙, 王福会. Cr对镍基合金在超临界水中氧化行为的影响研究[J]. 中国腐蚀与防护学报, 2018, 38(4): 358-364.
[7]	李越, 王剑, 张勇, 白晋钢, 胡亚迪, 乔永锋, 张彩丽, 韩培德. 2205双相不锈钢密闭容器中高温初始氧化过程分析[J]. 中国腐蚀与防护学报, 2018, 38(3): 296-302.
[8]	孙超, 杨潇, 文玉华. 表面溅射高含铝奥氏体不锈钢合金涂层对316不锈钢抗高温氧化性能的影响[J]. 中国腐蚀与防护学报, 2017, 37(6): 590-596.
[9]	赵展,李景阳,董建新,姚志浩,张麦仓. 925镍铁基耐蚀合金均匀化及高温氧化行为[J]. 中国腐蚀与防护学报, 2017, 37(1): 1-8.
[10]	朱明,周嘏玥,张慧慧. 316不锈钢在添加微量稀土元素硝酸熔盐中腐蚀行为研究[J]. 中国腐蚀与防护学报, 2017, 37(1): 16-22.
[11]	王喜忠,吴建颢,彭徽,郭洪波,宫声凯. 电子束物理气相沉积La₂Ce₂O₇热障涂层的高温燃气热腐蚀行为研究[J]. 中国腐蚀与防护学报, 2017, 37(1): 36-40.
[12]	谢冬柏,单国. 燃油火场环境中助燃剂的快速检验方法研究[J]. 中国腐蚀与防护学报, 2017, 37(1): 74-80.
[13]	杨甜甜,徐敬军,钱余海,李美栓. 石墨基体上ZrC/MoSi₂微叠层涂层的制备及抗超高温氧化性能[J]. 中国腐蚀与防护学报, 2016, 36(5): 476-482.
[14]	袁军涛, 王文, 朱圣龙, 王福会. Super 304H钢在700~900 ℃纯水蒸汽中的氧化行为[J]. 中国腐蚀与防护学报, 2014, 34(3): 218-224.
[15]	袁军涛, 吴细毛, 王文, 朱圣龙, 王福会. 晶粒尺寸对耐热钢在高温水蒸汽中的氧化行为的影响[J]. 中国腐蚀与防护学报, 2013, 33(4): 257-264.

Viewed

Full text

Abstract

Cited

Shared

Discussed