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中国腐蚀与防护学报  2014, Vol. 34 Issue (1): 65-69    DOI: 10.11902/1005.4537.2013.049
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
含水量对连铸铜包钢在大港土壤中腐蚀行为的影响
朱 敏 杜翠薇 黄 亮 刘智勇 赵天亮 李 琼 李晓刚
北京科技大学腐蚀与防护中心 北京 100083
Influence of Water Contents on Corrosion Behavior of Continuous Casting Copper-clad Steel in Dagang Soil
ZHU Min, DU Cuiwei, HUANG Liang, LIU Zhiyong, ZHAO Tianliang, LI Qiong, LI Xiaogang
Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China
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摘要 采用极化曲线和电化学阻抗技术对连铸铜包钢在含水量20%~30% (质量分数) 的大港滨海盐渍土中的腐蚀电化学行为进行研究。结果表明:埋样初期,连铸铜包钢腐蚀速率大致相等,含水量对其腐蚀行为影响较小,电极过程主要为活化控制;埋样后期,连铸铜包钢腐蚀速率先减小后趋于平稳,这是含水量对电极过程两个相反作用 (氧浓度降低的阻滞作用和环境水化的促进作用) 的综合作用结果,电极过程表现为阴极的氧扩散控制。
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朱敏
杜翠薇
黄亮
刘智勇
赵天亮
李琼
李晓刚
关键词:  连铸铜包钢  含水量  大港土壤  腐蚀行为    
Abstract: The corrosion behavior of continuous casting copper-clad steel in Dagang soil with 20%~30% water contents was studied by polarization curve measurement and EIS. It is shown that during the initial corrosion stage, the corrosion rates of continuous casting copper-clad steel are almost equal, which imply the water contents have little influence on the corrosion behavior. The control step for corrosion of continuous casting copper-clad steel in the soil is activation polarization process at the initial stage. During the later stage, the corrosion rates of continuous casting copper-clad steel decrease and then tend to be stable with the increase of water contents, which may be due to the synergistic effect of the two opposite factors i.e. the block effect with reducing oxygen and the stimulation effect with environmental water on the electrode process. However the corrosion behavior is mainly affected by oxygen diffusion control.
Key words:  continuous casting copper-clad steel    water content    Dagang soil    corrosion behavior
收稿日期:  2013-04-08                出版日期:  2014-02-20      发布日期:  2014-03-06      期的出版日期:  2014-02-20
ZTFLH:  TG172.4  
基金资助: 国家自然科学基金重点项目(51131001)和国家自然科学基金项目(51371036) 资助
通讯作者:  杜翠薇,E-mail:zmii2009@163.com   
作者简介:  朱敏,男,1985年生,博士生,研究方向为材料的腐蚀与防护
引用本文:    
朱敏, 杜翠薇, 黄亮, 刘智勇, 赵天亮, 李琼, 李晓刚. 含水量对连铸铜包钢在大港土壤中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2014, 34(1): 65-69.
ZHU Min,DU Cuiwei,HUANG Liang,LIU Zhiyong,ZHAO Tianliang,LI Qiong,LI Xiaogang. Influence of Water Contents on Corrosion Behavior of Continuous Casting Copper-clad Steel in Dagang Soil. Journal of Chinese Society for Corrosion and protection, 2014, 34(1): 65-69.
链接本文:  
http://www.jcscp.org/CN/10.11902/1005.4537.2013.049  或          http://www.jcscp.org/CN/Y2014/V34/I1/65
[1] Zhou P P, Wang S, Li Z Z, et al. Review of corrosion resistant metals for grounding [J]. Elec. Power Constr., 2010, 31(8): 51-54(周佩朋, 王森, 李志忠等. 耐蚀性金属接地材料研究综述 [J]. 电力建设, 2010, 31(8): 51-54)
[2] Weng Y F. Analysis of grounding connection cauterization and the suggestions for material selection [J]. Zhejiang Elec. Power, 2003, (4): 54-56(翁羽丰. 接地装置腐蚀分析及材料选用建议 [J]. 浙江电力, 2003,(4): 54-56)
[3] Li J L. Utility Electrical Grounding Technology [M]. Beijing: China Electric Power Press, 2002(李景禄. 实用电力接地技术 [M]. 北京:中国电力出版社, 2002)
[4] Yang D W, Li J L. Analysis on corrosion and anti-corrosion measure of substation grounding device [J]. Insul. Surg. Arresters, 2004,(2): 43-46(杨道武, 李景禄. 发电厂变电所接地装置的腐蚀及防腐蚀措施 [J]. 电瓷避雷器, 2004, (2): 43-46)
[1] Zhou P P, Wang S, Li Z Z, et al. Review of corrosion resistant metals for grounding [J]. Elec. Power Constr., 2010, 31(8): 51-54(周佩朋, 王森, 李志忠等. 耐蚀性金属接地材料研究综述 [J]. 电力建设, 2010, 31(8): 51-54)
[5] Riemer D, Orazem M. A mathematical model for the cathodic protection of tank bottoms [J]. Corros. Sci., 2005, 47(3): 849-868
[6] Thara A, Shinohara T. Influence of the alloy element on corrosion morphology of the low alloy steels exposed to the atmospheric environments [J]. Corros. Sci., 2005, 47(10): 2589-2598
[2] Weng Y F. Analysis of grounding connection cauterization and the suggestions for material selection [J]. Zhejiang Elec. Power, 2003, (4): 54-56(翁羽丰. 接地装置腐蚀分析及材料选用建议 [J]. 浙江电力, 2003,(4): 54-56)
[3] Li J L. Utility Electrical Grounding Technology [M]. Beijing: China Electric Power Press, 2002(李景禄. 实用电力接地技术 [M]. 北京:中国电力出版社, 2002)
[7] Hoffmeister H. Modeling of crevice corrosion of pure nickel by coupling of phase and polarization behavior at various pH, chloride, and oxygen levels [J]. Corrosion, 2005, 61(9): 880
[8] Gerwin W, Baumhauer R. Effect of soil parameters on the corrosion of archaeological metal finds [J]. Geoderma, 2000, 96(1): 63-80
[4] Yang D W, Li J L. Analysis on corrosion and anti-corrosion measure of substation grounding device [J]. Insul. Surg. Arresters, 2004,(2): 43-46(杨道武, 李景禄. 发电厂变电所接地装置的腐蚀及防腐蚀措施 [J]. 电瓷避雷器, 2004, (2): 43-46)
[5] Riemer D, Orazem M. A mathematical model for the cathodic protection of tank bottoms [J]. Corros. Sci., 2005, 47(3): 849-868
[9] Dong C F, Li X G, Wu J W. Review in experimentation and data processing soil corrosion [J]. Corros. Sci. Prot. Technol., 2003, 15: 154-160(董超芳, 李晓刚, 武俊伟. 土壤腐蚀的实验研究与数据处理 [J]. 腐蚀科学与防护技术, 2003, 15: 154-160)
[10] Chen X, Du C W, Li X G, et al. Influences of water content on the corrosion behavior of X70 steel in Dagang saline-alkaline soil [J]. Univ. Sci. Technol. Beijing, 2008, 30(7): 730-734(陈旭, 杜翠薇, 李晓刚等. 含水量对X70钢在大港滨海盐渍土壤中腐蚀行为的影响 [J]. 北京科技大学学报, 2008, 30(7): 730-734)
[6] Thara A, Shinohara T. Influence of the alloy element on corrosion morphology of the low alloy steels exposed to the atmospheric environments [J]. Corros. Sci., 2005, 47(10): 2589-2598
[7] Hoffmeister H. Modeling of crevice corrosion of pure nickel by coupling of phase and polarization behavior at various pH, chloride, and oxygen levels [J]. Corrosion, 2005, 61(9): 880
[11] Yang J P, Di Z, Weng Y J. Study on regional soil corrosiveness in Dagang oil field [J]. Corros. Sci. Prot. Technol., 1995, 7: 275-276(杨建平, 狄峥, 翁永基. 大港油田区域土壤腐蚀性研究 [J]. 腐蚀科学与防护技术, 1995, 7: 275-276)
[12] Cao C N, Zhang J Q. Electrochemical Impedance Spectroscopy [M]. Beijing: Science Press, 2004(曹楚南, 张鉴清. 电化学阻抗谱导论 [M]. 北京: 科学出版社, 2004)
[8] Gerwin W, Baumhauer R. Effect of soil parameters on the corrosion of archaeological metal finds [J]. Geoderma, 2000, 96(1): 63-80
[9] Dong C F, Li X G, Wu J W. Review in experimentation and data processing soil corrosion [J]. Corros. Sci. Prot. Technol., 2003, 15: 154-160(董超芳, 李晓刚, 武俊伟. 土壤腐蚀的实验研究与数据处理 [J]. 腐蚀科学与防护技术, 2003, 15: 154-160)
[13] Wang Y H, Wang J, Zhang J B. Influences of current density on the properties of micro-arc oxidation coatings on AZ91D Mg alloy [J]. J. Chin. Soc. Corros. Prot., 2005, 25(6): 332-335(王燕华, 王佳, 张际标. 电流密度对AZ91D镁合金微弧氧化膜性能的影响 [J]. 中国腐蚀与防护学报, 2005, 25(6): 332-335)
[14] Liang P, Li X G, Du C W, et al. Effect of dissolved oxygen on corrosion resistance of X80 pipeline steel in NS4 solution [J]. Corros. Sci. Prot. Technol., 2009, 21(1): 20-23(梁平, 李晓刚, 杜翠薇等. 溶解氧对X80管线钢在NS4溶液中腐蚀行为的影响 [J]. 腐蚀科学与防护技术, 2009, 21(1): 20-23)
[10] Chen X, Du C W, Li X G, et al. Influences of water content on the corrosion behavior of X70 steel in Dagang saline-alkaline soil [J]. Univ. Sci. Technol. Beijing, 2008, 30(7): 730-734(陈旭, 杜翠薇, 李晓刚等. 含水量对X70钢在大港滨海盐渍土壤中腐蚀行为的影响 [J]. 北京科技大学学报, 2008, 30(7): 730-734)
[15] Li J B, Zuo J E. Influence of temperature and sulfur ion on carbon dioxide corrosion behavior of N80 steel [J]. Corros. Sci. Prot. Technol., 2009, 21(1): 44-47(李金波, 左剑恶. 温度和硫离子对N80钢CO2腐蚀电化学行为的影响 [J]. 腐蚀科学与防护技术, 2009, 21(1): 44-47)
[11] Yang J P, Di Z, Weng Y J. Study on regional soil corrosiveness in Dagang oil field [J]. Corros. Sci. Prot. Technol., 1995, 7: 275-276(杨建平, 狄峥, 翁永基. 大港油田区域土壤腐蚀性研究 [J]. 腐蚀科学与防护技术, 1995, 7: 275-276)
[16] Wei B M. Theory and Application of Metal Corrosion [M]. Beijing: Chemistry Industry Press, 2004(魏宝明. 金属腐蚀理论及应用 [M]. 北京: 化学工业出版社, 2004)
[12] Cao C N, Zhang J Q. Electrochemical Impedance Spectroscopy [M]. Beijing: Science Press, 2004(曹楚南, 张鉴清. 电化学阻抗谱导论 [M]. 北京: 科学出版社, 2004)
[17] Li M C, Lin H C, Cao C N. Influence of moisture content on soil corrosion behavior of carbon steel [J]. Corros. Sci. Prot. Technol., 2000, 14(4): 218-221(李谋成, 林海潮, 曹楚南. 湿度对钢铁材料在中性土壤中腐蚀行为的影响 [J]. 腐蚀科学与防护技术, 2000, 14(4): 218-221)
[13] Wang Y H, Wang J, Zhang J B. Influences of current density on the properties of micro-arc oxidation coatings on AZ91D Mg alloy [J]. J. Chin. Soc. Corros. Prot., 2005, 25(6): 332-335(王燕华, 王佳, 张际标. 电流密度对AZ91D镁合金微弧氧化膜性能的影响 [J]. 中国腐蚀与防护学报, 2005, 25(6): 332-335)
[18] Gardiner C P, Melchers R E. Corrosion of mild steel in porous media [J]. Corros. Sci., 2002, 44: 2459-2478
[14] Liang P, Li X G, Du C W, et al. Effect of dissolved oxygen on corrosion resistance of X80 pipeline steel in NS4 solution [J]. Corros. Sci. Prot. Technol., 2009, 21(1): 20-23(梁平, 李晓刚, 杜翠薇等. 溶解氧对X80管线钢在NS4溶液中腐蚀行为的影响 [J]. 腐蚀科学与防护技术, 2009, 21(1): 20-23)
[19] Nie X H, Li X G, Du C W, et al. EIS analysis of Q235 corrosion in sea-shore salt soil with different water contents [J]. J. Mater. Eng., 2009, 6: 17-19(聂向辉, 李晓刚, 杜翠微等. Q235钢在不同含水量滨海盐土中腐蚀的电化学阻抗谱分析 [J]. 材料工程, 2009, 6: 17-19)
[15] Li J B, Zuo J E. Influence of temperature and sulfur ion on carbon dioxide corrosion behavior of N80 steel [J]. Corros. Sci. Prot. Technol., 2009, 21(1): 44-47(李金波, 左剑恶. 温度和硫离子对N80钢CO2腐蚀电化学行为的影响 [J]. 腐蚀科学与防护技术, 2009, 21(1): 44-47)
[16] Wei B M. Theory and Application of Metal Corrosion [M]. Beijing: Chemistry Industry Press, 2004(魏宝明. 金属腐蚀理论及应用 [M]. 北京: 化学工业出版社, 2004)
[17] Li M C, Lin H C, Cao C N. Influence of moisture content on soil corrosion behavior of carbon steel [J]. Corros. Sci. Prot. Technol., 2000, 14(4): 218-221(李谋成, 林海潮, 曹楚南. 湿度对钢铁材料在中性土壤中腐蚀行为的影响 [J]. 腐蚀科学与防护技术, 2000, 14(4): 218-221)
[18] Gardiner C P, Melchers R E. Corrosion of mild steel in porous media [J]. Corros. Sci., 2002, 44: 2459-2478
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