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中国腐蚀与防护学报  2014, Vol. 34 Issue (1): 82-88    DOI: 10.11902/1005.4537.2013.041
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
过量CO2气氛环境下青铜表面生成孔雀石锈蚀产物的模拟研究
吴涛涛1 孟威威1 鲍志荣1 李 洋2,3 潘春旭1,3
1. 武汉大学物理科学与技术学院和电子显微镜中心 武汉 430072;
2. 武汉大学历史学院 武汉 430072;
3. 武汉大学科技考古研究中心 武汉 430072
Formation of Malachite Rusts on Bronze in Environments with Excess of CO2
WU Taotao1, MENG Weiwei1, BAO Zhirong1, LI Yang2,3, PAN Chunxu1,3
1. School of Physics and Technology and Center for Electron Microscopy, Wuhan University, Wuhan 430072, China;
2. School of History, Wuhan University, Wuhan 430072, China;
3. Center for Archaeometry, Wuhan University, Wuhan 430072, China
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摘要 利用一种新型的盐溶液-蒸汽模拟技术,在过量CO2的气氛环境中模拟生成孔雀石等锈蚀产物,并利用光学显微镜、扫描电子显微镜、能谱仪、X射线衍射仪、Raman光谱仪等表征仪器,系统表征了锈蚀产物的微观组织和化学成分等。研究分析了在不同过量CO2的气氛环境下,青铜表面生成锈蚀产物的特征及其生长机理,为古代青铜器的保护提供了科学依据。
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关键词:  青铜  孔雀石  锈蚀产物  CO2气氛环境    
Abstract: The formation of rusts consisted mainly of malachite on bronze was simulated with a new process, by which the corrosion test of bronze samples was performed in controllable environments with excess of CO2 contents, water vapor and chlorine ions. The chemical composition, microstructure and phase constituents of the corrosion products were characterized by means of optical microscopy, scanning electron microscope (SEM) with energy dispersive spectrometer (EDS), X-ray diffraction (XRD), and Raman microscopy. The results revealed that the characteristics of corrosion products were related with the content of CO2 and H2O in the environment. The growth mechanism of the rusts in these environments was discussed and the suggestions for preservation of the ancient bronzes were proposed.
Key words:  bronze    malachite    corrosion product    CO2 atmosphere environment
收稿日期:  2013-04-01                出版日期:  2014-02-20      发布日期:  2014-03-06      期的出版日期:  2014-02-20
ZTFLH:  TG172.6  
  K876.41  
基金资助: 国家大学生创新创业计划项目 (111048620)和武汉市文化局项目资助
通讯作者:  潘春旭,E-mail:cxpan@whu.edu.cn   
作者简介:  吴涛涛,男,1990年生,本科生,研究方向为文物保护与科技考古
引用本文:    
吴涛涛, 孟威威, 鲍志荣, 李洋, 潘春旭. 过量CO2气氛环境下青铜表面生成孔雀石锈蚀产物的模拟研究[J]. 中国腐蚀与防护学报, 2014, 34(1): 82-88.
WU Taotao,MENG Weiwei,BAO Zhirong,LI Yang,,PAN Chunxu,. Formation of Malachite Rusts on Bronze in Environments with Excess of CO2. Journal of Chinese Society for Corrosion and protection, 2014, 34(1): 82-88.
链接本文:  
http://www.jcscp.org/CN/10.11902/1005.4537.2013.041  或          http://www.jcscp.org/CN/Y2014/V34/I1/82
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